Tailoring micro-mesoporosity in activated carbon fibers to enhance SO2 catalytic oxidation

Enhanced SO2 adsorption of activated carbon fibers is obtained by tailoring a specific micro-mesoporous structure in the fibers. This architecture is obtained via metal catalytic activation of the fibers with a novel precursor, cobalt naphthenate, which contrary to other precursors, also enhances spinnability and carbon fiber yield. In the SO2 oxidation, it is demonstrated that the combination of micropores and large mesopores is the main factor for an enhanced catalytic activity which is superior to that observed in other similar microporous activated carbon fibers. This provides an alternative way for the development of a new generation of catalytic material.

Saved in:
Bibliographic Details
Main Authors: Díez Nogués, Noel, Álvarez Rodríguez, Patricia, Granda Ferreira, Marcos, Blanco Rodríguez, Clara, Gryglewicz, Grazyna, Wróbel-Iwaniec, Iwona, Śliwak, Agata, Machnikowski, Jacek, Menéndez López, Rosa María
Format: artículo biblioteca
Language:English
Published: Elsevier 2014-04-24
Subjects:Carbon fiber, Cobalt naphthenate, Mesopores, Micropores, SO2 adsorption,
Online Access:http://hdl.handle.net/10261/114350
Tags: Add Tag
No Tags, Be the first to tag this record!