MELT-PROCESSING OF SBS/POLYANILINE-BASED BLENDS PROCESAMIENTO TÉRMICO DE MEZCLAS A BASE DE SBS Y POLIANILINA

Morphological analysis and electrical conductivity of composites obtained by melt-processing of blends of a polyaniline complex (PANICX) with styrene-butadiene-styrene (SBS) are reported. Blends with PANICX contents ranging from 1 to 50 wt% were first prepared using a two-piece batch mixer, followed by ram-extrusion to obtain cord-like extrudates. The microstructure was analyzed by SEM, and conductivity was evaluated with a Keithley electrometer. The blends’ rheological behavior was also studied. Evidence of formation of well-defined elongated structures was found in most of the extrudates. The extrudates’ conductivity was considerably low. Inhomogeneityrelated problems were observed such as erratic behavior of pressure, “melt-fracture” during the extrusion, and extrudates with irregular microstructure and very low conductivity. This occurred because same size batches were used regardless of blends’ comp

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Bibliographic Details
Main Author: RICARDO HERBE CRUZ ESTRADA
Format: info:eu-repo/semantics/article biblioteca
Subjects:info:eu-repo/classification/cti/7,
Online Access:http://cicy.repositorioinstitucional.mx/jspui/handle/1003/84
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