Silicates as alternative pretreatment for cellulose pulp to obtain nanofibrils for application in biodegradable packaging: a technical review.

ABSTRACT Background: The production of cellulose microfibrils/nanofibrils (CMF/CNF) has attracted increasing attention in recent decades due to their excellent barrier, mechanical, and surface chemistry properties. However, large-scale industrial production of CMF/CNF has been a major challenge due to their high energy consumption, limiting their application. In this context, in recent years many studies have focused on developing pre-treatments designed to facilitate the fibrillation of CMF/CNF by reducing energy consumption during their production. This review highlights the latest advances in the use of silicates as chemical pre-treatments for CMF/CNF production, covering the main aspects related to the effects of chemical modification on the production and the properties of materials for application in biodegradable packaging. Results: Energy consumption reductions of up to 30% were achieved by pretreating cellulose pulps using silicates. In addition, the pre-treatments resulted in smaller CMF/CNF diameters and greater individualization of the nanofibrils. Studies evaluating the thermal stability, hydrophobicity, mechanical properties, and porosity of CMF/CNF pre-treated with silicates have reported promising results. The application of CMF/CNF pretreated with calcium and magnesium silicates in cardboard coating resulted in packaging with low water vapor permeability and high ductility. Conclusion: Silicates interact well with cellulose surfaces, making them a promising material for the chemical pre-treatment of CMF/CNF. Furthermore, the modification by silicates could be an interesting strategy for expanding the use of CMF/CNF in the development of new products.

Bibliographic Details

Main Authors:	MASCARENHAS, A. R. P., SCATOLINO, M. V., MEDEIROS, D. T., BATISTA, F. G., SETTER, C., MELO, R. R. de, MARTINS, M. A., TONOLI, G. H. D.
Other Authors:	FEDERAL UNIVERSITY OF RONDÔNIA (UNIR); STATE UNIVERSITY OF AMAPÁ (UEAP); FEDERAL UNIVERSITY OF LAVRAS (UFLA); FEDERAL UNIVERSITY OF LAVRAS (UFLA); FEDERAL UNIVERSITY OF LAVRAS (UFLA); FEDERAL UNIVERSITY OF THE SEMIARID (UFERSA); MARIA ALICE MARTINS, CNPDIA; FEDERAL UNIVERSITY OF LAVRAS (UFLA).
Format:	Artigo de periódico biblioteca
Language:	eng
Published:	2024-09-12
Subjects:	Barrier properties, Energy consumption, Fiber modification, Paper coating,
Online Access:	http://www.alice.cnptia.embrapa.br/alice/handle/doc/1167344
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