Inorganic Thermochromism [electronic resource] /
A. Introduction -- A.I Definition of “Inorganic Thermochromism” and the Aim of this Book -- A.II Some Common Examples of Inorganic Thermochromism -- B. Thermochromic and Chromotropic Phenomena of Cobalt(II) Chloride Solutions and Related Systems -- B.I Introductory Remarks: Visual Observations on Aqueous and Alcoholic Solutions of Cobalt(II) Chloride -- B.II Low-Temperature Spectrophotometric Studies on Alcoholic Solutions of Cobah(II) Chloride -- B.III Effects of Water, High Pressure and Dilution on the Spectra of Alcoholic Solutions of Cobalt(II) Chloride -- B.IV Thermochromic Equilibria of Cobalt(II) Chloride in Aqueous Solutions -- B.V Chromotropic Phenomena of Cobalt(II) Chloride in Aprotic Solvents -- B.VI Chromotropic Phenomena of Other Cobalt(II) Salts in Aqueous and Organic Solvents -- B.VII Chromotropic Phenomena of Copper(II) and Nickel(II) Halides in Solution -- C. Thermochromism of Nickel(II) Chelates in Solution -- C.I Introduction -- C.II Tetrammine-type Chelates: Octahedral-Square Planar Equilibria -- C.III ß-Diketonate Chelates: Monomer-Polymer Equilibria -- C.IV Mixed Diamine-ß-Diketonate Chelates: Solvatochromic and Thermochromic Equilibria Governed by the Coordinating Power (Donor Number) of the Solvent -- C.V Chelates of Schiff Bases and Related Ligands: Tetrahedral-Square Planar Equilibria -- C.VI Thermochromic Systems Involving Formation of Five-Coordinate Complexes and Linkage Isomerization -- D. Chromotropic Phenomena of Copper(II) Chelates -- D.I Introduction: Structure and Spectra of Copper(II) Chelates -- D.II Acetylacetonates and Tetrammine-type Complexes -- D.III Mixed Diamine-?-Diketonate Chelates -- Ë. Miscellaneous Chromotropic Phenomena Observed in Solutions of Metallic Complexes -- E.I Introduction -- E.II Spin-Crossover in Iron(II) and Iron(III) Complexes Observed as Solution Thermochromism -- E.III Iron(II) Cyanide-(Heterocyclic N-Base) Mixed Complexes: Solvatochromism Caused by Acceptor Solvents and Ions -- E.IV Solvatochromism of Oxovanadium(IV) ?-Diketonates -- E.V Thermochromism of Metal Chelates with Triphenylmethane Complexones in Aqueous Solutions -- E. VI Thermochromism and Solvatochromism Accompanied by the Formation of Ligand Radicals in Solution -- F. Thermochromism of Transition Metal Complexes in the Solid State -- F.I Introduction -- F.II Irreversible Thermochromism -- F.III Reversible Thermochromism -- F.IV Practical Applications of Solid-State Thermochromism: Color Indicators for Temperature Changes -- Concluding Remarks.
Main Authors: | , , |
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Format: | Texto biblioteca |
Language: | eng |
Published: |
Berlin, Heidelberg : Springer Berlin Heidelberg,
1987
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Subjects: | Chemistry., Inorganic chemistry., Physical chemistry., Inorganic Chemistry., Physical Chemistry., |
Online Access: | http://dx.doi.org/10.1007/978-3-642-51017-5 |
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