Molecular Design of Tautomeric Compounds [electronic resource] /

1. The Problem of Tautomerism -- 1. Tautomerism as Dynamic Isomerism -- 2. Degenerate Tautomerism -- 3. Methods for Investigating Tautomeric Systems -- 4. Butlerov’s and Laar’s Tautomeric Systems -- 5. Tautomerism and the Mechanisms of Organic Reactions -- 6. Classification of Tautomeric Reactions -- 7. Conclusion -- References -- 2. Carbonotropy -- 1. The Problem of Carbonotropy -- 2. Sigmatropic Acyl and Aryl Rearrangements -- 3. Acylotropic Tautomerism -- 4. Tautomeric Rearrangements of Aryl Groups -- 5. Carbonotropic Tautomerism in Ions, Radicals and Cyclopolyenes -- References -- 3. General Principles of the Design of Tautomeric Systems -- 1. Possibilities of Quantum Mechanical Prediction of Tautomeric Reactions -- 2. Stereochemical Approach to the Design of Tautomeric Compounds -- References -- 4. The Mechanisms of Nucleophilic Substitution at the Main Group Element and Design of Intramolecular Tautomeric Systems -- 1. Tautomeric Rearrangements of Carbon-containing Groups -- 2. Silylotropic Tautomerism -- 3. Tautomeric Migrations of Phosphorus-containing Groups -- 4. Tautomeric Rearrangements of As-containing Groups -- 5. Tautomeric Rearrangements of Sulfur-containing Groups -- References -- 5. Dyotropic and Polytropic Tautomeric Systems -- 1. Scope and Definition -- 2. The Mechanism and Energetics of the Dyotropic Reactions -- References -- 6. Dissociative and Photochemical Mechanisms of Intramolecular Tautomerism -- 1. Heterolytic Dissociative Mechanism -- 2. Homolytic Dissociative Mechanism -- 3. Ion-Radical Mechanism -- 4. Photo-Initiated Carbonotropic Rearrangements -- References.

Bibliographic Details

Main Authors:	Minkin, V. I. editor., Olekhnovich, L. P. editor., Zhdanov, Yu. A. editor., SpringerLink (Online service)
Format:	Texto biblioteca
Language:	eng
Published:	Dordrecht : Springer Netherlands, 1988
Subjects:	Chemistry., Physical chemistry., Physical Chemistry.,
Online Access:	http://dx.doi.org/10.1007/978-94-009-1429-2
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