NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in the post-reaction mixture. The amount of product formed depends upon the nature of the amine coordinated to the rhodium center
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| Main Authors: | , , , , , , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedad Chilena de Química
2007
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| Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300014 |
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