NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in the post-reaction mixture. The amount of product formed depends upon the nature of the amine coordinated to the rhodium center
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Sociedad Chilena de Química
2007
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| Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300014 |
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oai:scielo:S0717-970720070003000142007-11-29NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDSBARTOLINP,MMOLINA,J.ORTEGA,M. CSOJO,PPARDEY,A. JLONGO,C.MOYA,S.A.FEAZELL,R. P Catalysis nitrobenzene reduction rhodium complexes carbon monoxide The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in the post-reaction mixture. The amount of product formed depends upon the nature of the amine coordinated to the rhodium centerinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.52 n.3 20072007-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300014en10.4067/S0717-97072007000300014 |
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BARTOLINP,M MOLINA,J. ORTEGA,M. C SOJO,P PARDEY,A. J LONGO,C. MOYA,S.A. FEAZELL,R. P |
| spellingShingle |
BARTOLINP,M MOLINA,J. ORTEGA,M. C SOJO,P PARDEY,A. J LONGO,C. MOYA,S.A. FEAZELL,R. P NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS |
| author_facet |
BARTOLINP,M MOLINA,J. ORTEGA,M. C SOJO,P PARDEY,A. J LONGO,C. MOYA,S.A. FEAZELL,R. P |
| author_sort |
BARTOLINP,M |
| title |
NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS |
| title_short |
NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS |
| title_full |
NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS |
| title_fullStr |
NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS |
| title_full_unstemmed |
NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS |
| title_sort |
nitrobenzene reduction catalized by soluble carbonylrhodium complexes of methyl and dimethyl pyridine ligands |
| description |
The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in the post-reaction mixture. The amount of product formed depends upon the nature of the amine coordinated to the rhodium center |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2007 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300014 |
| work_keys_str_mv |
AT bartolinpm nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT molinaj nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT ortegamc nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT sojop nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT pardeyaj nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT longoc nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT moyasa nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands AT feazellrp nitrobenzenereductioncatalizedbysolublecarbonylrhodiumcomplexesofmethylanddimethylpyridineligands |
| _version_ |
1755993412039868416 |