EVALUATION OF POLY(VINYL ALCOHOL) ADDITION EFFECT ON NANOFIBRILLATED CELLULOSE FILMS CHARACTERISTICS
ABSTRACT In this study, based on the mechanical shear treatment, the cellulosic pulp was fibrillated in nanofibrils dispersed in aqueous suspension. Nanofibrillated Cellulose (NFC) matrix - Polyvinyl Alcohol (PVA) nanocomposite films’ were prepared by casting from NFC/PVA suspension mixtures. The thermal and mechanical properties of the obtained films were evaluated. Low levels (2, 5 and 10 wt%) of PVA were used as an additive in a nanofibrillated cellulose (NFC) matrix. The predominant use of NFC, with superior properties due to its purity, with an efficient and environmentally friendly method, has allowed the production of NFC-based biodegradable materials with enhanced properties for high-level applications. The addition of PVA to the NFC matrix produced positive results, as it causes little aesthetic interference, without changes in surface brightness. After the addition of PVA the films showed a great gain in mechanical strength, increasing by 24% in Young’s modulus with the addition of 10% PVA. Even after addition, the samples’ chemical composition remains unchanged and the mixture shows a decrease in the film surface hydrophilicity when compared to pure NFC. Composite material thermal analysis indicates that thermal degradation temperatures remain unchanged after the addition of PVA. Although PVA is not very temperature resistant, in the proportions used, NFC thermal resistance is preserved.
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UFLA - Universidade Federal de Lavras
2020
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oai:scielo:S0104-776020200001000012020-06-16EVALUATION OF POLY(VINYL ALCOHOL) ADDITION EFFECT ON NANOFIBRILLATED CELLULOSE FILMS CHARACTERISTICSSilva,Eliane Lopes daReis,Cibelle AmaralVieira,Helena CristinaSantos,Joielan Xipaia dosNisgoski,SilvanaSaul,Cyro KetzerMuñiz,Graciela Inés Bolzon de Cellulose Nanofibers Composite Films Mechanical properties PVA Addition ABSTRACT In this study, based on the mechanical shear treatment, the cellulosic pulp was fibrillated in nanofibrils dispersed in aqueous suspension. Nanofibrillated Cellulose (NFC) matrix - Polyvinyl Alcohol (PVA) nanocomposite films’ were prepared by casting from NFC/PVA suspension mixtures. The thermal and mechanical properties of the obtained films were evaluated. Low levels (2, 5 and 10 wt%) of PVA were used as an additive in a nanofibrillated cellulose (NFC) matrix. The predominant use of NFC, with superior properties due to its purity, with an efficient and environmentally friendly method, has allowed the production of NFC-based biodegradable materials with enhanced properties for high-level applications. The addition of PVA to the NFC matrix produced positive results, as it causes little aesthetic interference, without changes in surface brightness. After the addition of PVA the films showed a great gain in mechanical strength, increasing by 24% in Young’s modulus with the addition of 10% PVA. Even after addition, the samples’ chemical composition remains unchanged and the mixture shows a decrease in the film surface hydrophilicity when compared to pure NFC. Composite material thermal analysis indicates that thermal degradation temperatures remain unchanged after the addition of PVA. Although PVA is not very temperature resistant, in the proportions used, NFC thermal resistance is preserved.info:eu-repo/semantics/openAccessUFLA - Universidade Federal de LavrasCERNE v.26 n.1 20202020-03-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-77602020000100001en10.1590/01047760202026012654 |
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Silva,Eliane Lopes da Reis,Cibelle Amaral Vieira,Helena Cristina Santos,Joielan Xipaia dos Nisgoski,Silvana Saul,Cyro Ketzer Muñiz,Graciela Inés Bolzon de |
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Silva,Eliane Lopes da Reis,Cibelle Amaral Vieira,Helena Cristina Santos,Joielan Xipaia dos Nisgoski,Silvana Saul,Cyro Ketzer Muñiz,Graciela Inés Bolzon de EVALUATION OF POLY(VINYL ALCOHOL) ADDITION EFFECT ON NANOFIBRILLATED CELLULOSE FILMS CHARACTERISTICS |
author_facet |
Silva,Eliane Lopes da Reis,Cibelle Amaral Vieira,Helena Cristina Santos,Joielan Xipaia dos Nisgoski,Silvana Saul,Cyro Ketzer Muñiz,Graciela Inés Bolzon de |
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Silva,Eliane Lopes da |
title |
EVALUATION OF POLY(VINYL ALCOHOL) ADDITION EFFECT ON NANOFIBRILLATED CELLULOSE FILMS CHARACTERISTICS |
title_short |
EVALUATION OF POLY(VINYL ALCOHOL) ADDITION EFFECT ON NANOFIBRILLATED CELLULOSE FILMS CHARACTERISTICS |
title_full |
EVALUATION OF POLY(VINYL ALCOHOL) ADDITION EFFECT ON NANOFIBRILLATED CELLULOSE FILMS CHARACTERISTICS |
title_fullStr |
EVALUATION OF POLY(VINYL ALCOHOL) ADDITION EFFECT ON NANOFIBRILLATED CELLULOSE FILMS CHARACTERISTICS |
title_full_unstemmed |
EVALUATION OF POLY(VINYL ALCOHOL) ADDITION EFFECT ON NANOFIBRILLATED CELLULOSE FILMS CHARACTERISTICS |
title_sort |
evaluation of poly(vinyl alcohol) addition effect on nanofibrillated cellulose films characteristics |
description |
ABSTRACT In this study, based on the mechanical shear treatment, the cellulosic pulp was fibrillated in nanofibrils dispersed in aqueous suspension. Nanofibrillated Cellulose (NFC) matrix - Polyvinyl Alcohol (PVA) nanocomposite films’ were prepared by casting from NFC/PVA suspension mixtures. The thermal and mechanical properties of the obtained films were evaluated. Low levels (2, 5 and 10 wt%) of PVA were used as an additive in a nanofibrillated cellulose (NFC) matrix. The predominant use of NFC, with superior properties due to its purity, with an efficient and environmentally friendly method, has allowed the production of NFC-based biodegradable materials with enhanced properties for high-level applications. The addition of PVA to the NFC matrix produced positive results, as it causes little aesthetic interference, without changes in surface brightness. After the addition of PVA the films showed a great gain in mechanical strength, increasing by 24% in Young’s modulus with the addition of 10% PVA. Even after addition, the samples’ chemical composition remains unchanged and the mixture shows a decrease in the film surface hydrophilicity when compared to pure NFC. Composite material thermal analysis indicates that thermal degradation temperatures remain unchanged after the addition of PVA. Although PVA is not very temperature resistant, in the proportions used, NFC thermal resistance is preserved. |
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UFLA - Universidade Federal de Lavras |
publishDate |
2020 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-77602020000100001 |
work_keys_str_mv |
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