The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)

The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)

The complexes of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II) have been synthesized as polycrystalline solids, and characterized by elemental analysis, spectroscopy, magnetic studies and also by X-ray diffraction and thermogravimetric measurements. The analysed complexes have the following colours: pink for Co(II), green for Ni(II), blue for Cu(II) and a pale pink for Mn(II) compounds. The carboxylate group binds as monodentate and bidentate ligands. On heating to 1173K in air the complexes decompose in several steps. At first, they dehydrate in one step to anhydrous salts, that next decompose to the oxides of respective metals. Their magnetic moments were determined in the range of 76-303K. The results reveal them to be high-spin complexes of weak ligand fields.

Saved in:
Bibliographic Details
Main Authors: Ferenc,W, Bernat,M, Sarzynski,J, Paszkowska,B
Format: Digital revista
Language:English
Published: Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP 2008
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702008000100001
Tags: Add Tag
No Tags, Be the first to tag this record!
id oai:scielo:S0100-46702008000100001
record_format ojs
spelling oai:scielo:S0100-467020080001000012008-05-21The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)Ferenc,WBernat,MSarzynski,JPaszkowska,B 4-chlorophenoxyacetates thermal stability magnetic properties of Mn(II) Co(II) Ni(II) Cu(II) The complexes of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II) have been synthesized as polycrystalline solids, and characterized by elemental analysis, spectroscopy, magnetic studies and also by X-ray diffraction and thermogravimetric measurements. The analysed complexes have the following colours: pink for Co(II), green for Ni(II), blue for Cu(II) and a pale pink for Mn(II) compounds. The carboxylate group binds as monodentate and bidentate ligands. On heating to 1173K in air the complexes decompose in several steps. At first, they dehydrate in one step to anhydrous salts, that next decompose to the oxides of respective metals. Their magnetic moments were determined in the range of 76-303K. The results reveal them to be high-spin complexes of weak ligand fields.info:eu-repo/semantics/openAccessFundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESPEclética Química v.33 n.1 20082008-01-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702008000100001en10.1590/S0100-46702008000100001
institution SCIELO
collection OJS
country Brasil
countrycode BR
component Revista
access En linea
databasecode rev-scielo-br
tag revista
region America del Sur
libraryname SciELO
language English
format Digital
author Ferenc,W
Bernat,M
Sarzynski,J
Paszkowska,B
spellingShingle Ferenc,W
Bernat,M
Sarzynski,J
Paszkowska,B
The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)
author_facet Ferenc,W
Bernat,M
Sarzynski,J
Paszkowska,B
author_sort Ferenc,W
title The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)
title_short The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)
title_full The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)
title_fullStr The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)
title_full_unstemmed The physico-chemical properties of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II)
title_sort physico-chemical properties of 4-chlorophenoxyacetates of mn(ii), co(ii), ni(ii) and cu(ii)
description The complexes of 4-chlorophenoxyacetates of Mn(II), Co(II), Ni(II) and Cu(II) have been synthesized as polycrystalline solids, and characterized by elemental analysis, spectroscopy, magnetic studies and also by X-ray diffraction and thermogravimetric measurements. The analysed complexes have the following colours: pink for Co(II), green for Ni(II), blue for Cu(II) and a pale pink for Mn(II) compounds. The carboxylate group binds as monodentate and bidentate ligands. On heating to 1173K in air the complexes decompose in several steps. At first, they dehydrate in one step to anhydrous salts, that next decompose to the oxides of respective metals. Their magnetic moments were determined in the range of 76-303K. The results reveal them to be high-spin complexes of weak ligand fields.
publisher Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP
publishDate 2008
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702008000100001
work_keys_str_mv AT ferencw thephysicochemicalpropertiesof4chlorophenoxyacetatesofmniicoiiniiiandcuii
AT bernatm thephysicochemicalpropertiesof4chlorophenoxyacetatesofmniicoiiniiiandcuii
AT sarzynskij thephysicochemicalpropertiesof4chlorophenoxyacetatesofmniicoiiniiiandcuii
AT paszkowskab thephysicochemicalpropertiesof4chlorophenoxyacetatesofmniicoiiniiiandcuii
AT ferencw physicochemicalpropertiesof4chlorophenoxyacetatesofmniicoiiniiiandcuii
AT bernatm physicochemicalpropertiesof4chlorophenoxyacetatesofmniicoiiniiiandcuii
AT sarzynskij physicochemicalpropertiesof4chlorophenoxyacetatesofmniicoiiniiiandcuii
AT paszkowskab physicochemicalpropertiesof4chlorophenoxyacetatesofmniicoiiniiiandcuii
_version_ 1756387934971363328

Similar Items