ELETRODOS DE FTO MODIFICADOS POR ELETRODEPOSIÇÃO DIRETA DE OURO: PRODUÇÃO, CARACTERIZAÇÃO E APLICAÇÃO COMO SENSOR ELETROQUÍMICO
Chemically modified electrodes have been studied to obtain new and better electrochemical sensors. Transparent conductive oxides, such as fluorine-doped tin-oxide (FTO), shows electrical conductivity comparable to metals and are potential candidates for new sensors. In this work, FTO was modified by gold electrodeposition from chlorine-auric acid solution using cyclic voltammetry (CV) technique. A set of different materials were produced, varying the scan number. Scanning electron microscopy and electrochemical impedance spectroscopy were performed for the characterization of electrodes surfaces. From this analysis was possible to observe the resistive, capacitive and difusional aspects from all kind of modified electrodes produced, establishing a relationship between this parameters and the scan number. The electrode with 100 scans of CV presented better characteristics for an electrochemical sensor; it has the lowest global impedance and rising of capacitive behavior (related to electrical double layer formation) at lower frequencies. This electrode was tested for paracetamol and caffeine detection. The results showed a high specificity, decreased oxidation potential (0.58 V and 0.97 Vvs. SCE, for paracetamol and caffeine, respectively) and low detection limits (0.82 and 0.052 µmol L-1).
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Sociedade Brasileira de Química
2016
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oai:scielo:S0100-404220160002001462016-03-29ELETRODOS DE FTO MODIFICADOS POR ELETRODEPOSIÇÃO DIRETA DE OURO: PRODUÇÃO, CARACTERIZAÇÃO E APLICAÇÃO COMO SENSOR ELETROQUÍMICOOliveira,Rogério dePissetti,Fabio LuizLucho,Alzira M. S. FTO electrodeposition electrochemical impedance spectroscopy Chemically modified electrodes have been studied to obtain new and better electrochemical sensors. Transparent conductive oxides, such as fluorine-doped tin-oxide (FTO), shows electrical conductivity comparable to metals and are potential candidates for new sensors. In this work, FTO was modified by gold electrodeposition from chlorine-auric acid solution using cyclic voltammetry (CV) technique. A set of different materials were produced, varying the scan number. Scanning electron microscopy and electrochemical impedance spectroscopy were performed for the characterization of electrodes surfaces. From this analysis was possible to observe the resistive, capacitive and difusional aspects from all kind of modified electrodes produced, establishing a relationship between this parameters and the scan number. The electrode with 100 scans of CV presented better characteristics for an electrochemical sensor; it has the lowest global impedance and rising of capacitive behavior (related to electrical double layer formation) at lower frequencies. This electrode was tested for paracetamol and caffeine detection. The results showed a high specificity, decreased oxidation potential (0.58 V and 0.97 Vvs. SCE, for paracetamol and caffeine, respectively) and low detection limits (0.82 and 0.052 µmol L-1).info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaQuímica Nova v.39 n.2 20162016-02-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000200146pt10.5935/0100-4042.20160011 |
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| author |
Oliveira,Rogério de Pissetti,Fabio Luiz Lucho,Alzira M. S. |
| spellingShingle |
Oliveira,Rogério de Pissetti,Fabio Luiz Lucho,Alzira M. S. ELETRODOS DE FTO MODIFICADOS POR ELETRODEPOSIÇÃO DIRETA DE OURO: PRODUÇÃO, CARACTERIZAÇÃO E APLICAÇÃO COMO SENSOR ELETROQUÍMICO |
| author_facet |
Oliveira,Rogério de Pissetti,Fabio Luiz Lucho,Alzira M. S. |
| author_sort |
Oliveira,Rogério de |
| title |
ELETRODOS DE FTO MODIFICADOS POR ELETRODEPOSIÇÃO DIRETA DE OURO: PRODUÇÃO, CARACTERIZAÇÃO E APLICAÇÃO COMO SENSOR ELETROQUÍMICO |
| title_short |
ELETRODOS DE FTO MODIFICADOS POR ELETRODEPOSIÇÃO DIRETA DE OURO: PRODUÇÃO, CARACTERIZAÇÃO E APLICAÇÃO COMO SENSOR ELETROQUÍMICO |
| title_full |
ELETRODOS DE FTO MODIFICADOS POR ELETRODEPOSIÇÃO DIRETA DE OURO: PRODUÇÃO, CARACTERIZAÇÃO E APLICAÇÃO COMO SENSOR ELETROQUÍMICO |
| title_fullStr |
ELETRODOS DE FTO MODIFICADOS POR ELETRODEPOSIÇÃO DIRETA DE OURO: PRODUÇÃO, CARACTERIZAÇÃO E APLICAÇÃO COMO SENSOR ELETROQUÍMICO |
| title_full_unstemmed |
ELETRODOS DE FTO MODIFICADOS POR ELETRODEPOSIÇÃO DIRETA DE OURO: PRODUÇÃO, CARACTERIZAÇÃO E APLICAÇÃO COMO SENSOR ELETROQUÍMICO |
| title_sort |
eletrodos de fto modificados por eletrodeposição direta de ouro: produção, caracterização e aplicação como sensor eletroquímico |
| description |
Chemically modified electrodes have been studied to obtain new and better electrochemical sensors. Transparent conductive oxides, such as fluorine-doped tin-oxide (FTO), shows electrical conductivity comparable to metals and are potential candidates for new sensors. In this work, FTO was modified by gold electrodeposition from chlorine-auric acid solution using cyclic voltammetry (CV) technique. A set of different materials were produced, varying the scan number. Scanning electron microscopy and electrochemical impedance spectroscopy were performed for the characterization of electrodes surfaces. From this analysis was possible to observe the resistive, capacitive and difusional aspects from all kind of modified electrodes produced, establishing a relationship between this parameters and the scan number. The electrode with 100 scans of CV presented better characteristics for an electrochemical sensor; it has the lowest global impedance and rising of capacitive behavior (related to electrical double layer formation) at lower frequencies. This electrode was tested for paracetamol and caffeine detection. The results showed a high specificity, decreased oxidation potential (0.58 V and 0.97 Vvs. SCE, for paracetamol and caffeine, respectively) and low detection limits (0.82 and 0.052 µmol L-1). |
| publisher |
Sociedade Brasileira de Química |
| publishDate |
2016 |
| url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000200146 |
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