Pyrolysis of glycerol over activated carbons for syngas production

Pyrolysis of glycerol over activated carbons for syngas production

6 pages, 4 figures.-- Article in press.

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Main Authors: Fernández Díez, Yolanda, Arenillas de la Puente, Ana, Díez Díaz-Estébanez, María Antonia, Pis Martínez, José Juan, Menéndez Díaz, José Ángel
Format: artículo biblioteca
Language:English
Published: Elsevier 2009-01-28
Subjects:Glycerol, Microwave, Activated carbon, Syngas,
Online Access:http://hdl.handle.net/10261/11286
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spelling dig-incar-es-10261-112862018-11-15T10:33:04Z Pyrolysis of glycerol over activated carbons for syngas production Fernández Díez, Yolanda Arenillas de la Puente, Ana Díez Díaz-Estébanez, María Antonia Pis Martínez, José Juan Menéndez Díaz, José Ángel Glycerol Microwave Activated carbon Syngas 6 pages, 4 figures.-- Article in press. The pyrolysis of glycerol was carried out over carbonaceous catalysts to produce synthesis gas (up to 81 vol.%). The catalytic effect of two activated carbons was tested and compared with quartz glass chips as packing materials in a fixed-bed reactor. The main advantage of using a carbonaceous catalyst seems to be its higher selectivity toward hydrogen, resulting in a synthesis gas with a greater H2/CO ratio. The influence of the heating method (electrical furnace and microwave oven) and temperature (from 400 to 900 °C) on the pyrolysis of glycerol over a selected activated carbon was also studied. As a result, an elevated gas fraction with a higher H2 + CO composition was obtained under microwave heating, even at low temperatures. This proves that microwave heating could be used to upgrade the industrial surplus generated from bio-diesel production. Y. Fernández is grateful to CSIC of Spain and the European Social Fund (ESF) for financial support under the Ph.D. grant I3P-BDP-2006. Financial support from the PCTI-Asturias (Project PEST08-03) is also acknowledged. Peer reviewed 2009-03-05T17:02:13Z 2009-03-05T17:02:13Z 2009-01-28 artículo http://purl.org/coar/resource_type/c_6501 Journal of Analytical and Applied Pyrolysis (2009), doi: 10.1016/j.jaap.2009.01.004 0165-2370 http://hdl.handle.net/10261/11286 10.1016/j.jaap.2009.01.004 en http://dx.doi.org/10.1016/j.jaap.2009.01.004 none 9211995 bytes application/pdf Elsevier
institution INCAR ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-incar-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del INCAR España
language English
topic Glycerol
Microwave
Activated carbon
Syngas
Glycerol
Microwave
Activated carbon
Syngas
spellingShingle Glycerol
Microwave
Activated carbon
Syngas
Glycerol
Microwave
Activated carbon
Syngas
Fernández Díez, Yolanda
Arenillas de la Puente, Ana
Díez Díaz-Estébanez, María Antonia
Pis Martínez, José Juan
Menéndez Díaz, José Ángel
Pyrolysis of glycerol over activated carbons for syngas production
description 6 pages, 4 figures.-- Article in press.
format artículo
topic_facet Glycerol
Microwave
Activated carbon
Syngas
author Fernández Díez, Yolanda
Arenillas de la Puente, Ana
Díez Díaz-Estébanez, María Antonia
Pis Martínez, José Juan
Menéndez Díaz, José Ángel
author_facet Fernández Díez, Yolanda
Arenillas de la Puente, Ana
Díez Díaz-Estébanez, María Antonia
Pis Martínez, José Juan
Menéndez Díaz, José Ángel
author_sort Fernández Díez, Yolanda
title Pyrolysis of glycerol over activated carbons for syngas production
title_short Pyrolysis of glycerol over activated carbons for syngas production
title_full Pyrolysis of glycerol over activated carbons for syngas production
title_fullStr Pyrolysis of glycerol over activated carbons for syngas production
title_full_unstemmed Pyrolysis of glycerol over activated carbons for syngas production
title_sort pyrolysis of glycerol over activated carbons for syngas production
publisher Elsevier
publishDate 2009-01-28
url http://hdl.handle.net/10261/11286
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AT pismartinezjosejuan pyrolysisofglyceroloveractivatedcarbonsforsyngasproduction
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