Sorption of Remazol Black B dye in alluvial soils of the Capibaribe River Basin, Pernambuco, Brazil

Abstract Wastewater from textile industries is loaded with synthetic dyes. These effluents are often not adequately treated, affecting the soil and groundwater quality and leading to environmental contamination. The Agreste mesoregion of the state of Pernambuco is home to one of the largest textile centers in Brazil. This work therefore aims to study the behavior of Remazol Black B (RB5) dye in subsurface mediums in this region. The kinetics and isotherm sorption experiments allowed an evaluation of RB5 retention capacity in two layers of alluvial soil of the dry riverbed of the Capibaribe Basin. The maximum sorption rate was 81.81 mg kg-1 and 21.7 mg kg-1 for the loamy sand and sand layers, respectively. The Pseudo-second order kinetic model described more appropriately the sorption kinetics for both soils. The isotherms behavior was nonlinear, and Freundlich model was the most suitable to describe this process for both soils, presenting KF values of 8.6407 L kg-1 for loamy sand and 0.1868 L kg-1 for sand. The isotherm parameters confirm a more significant interaction of RB5 with the loamy sand layer than with the sand layer, indicating lower leaching in the first layer, which is less mobile for RB5 contamination. Furthermore, the different sorption rates for both soils indicate the importance of studying the soil as a heterogeneous profile.

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Main Authors: Alves,Adriana Thays Araújo, Silva,Luisa Thaynara Muricy de Souza, Alcântara,Lucas Ravellys Pyrrho de, Barros,Vitor Hugo de Oliveira, Santos Neto,Severino Martins dos, Lima,Valmir Félix de, Lima,José Romualdo de Sousa, Coutinho,Artur Paiva, Antonino,Antonio Celso Dantas
Format: Digital revista
Language:English
Published: Instituto de Pesquisas Ambientais em Bacias Hidrográficas 2020
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1980-993X2020000200310
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spelling oai:scielo:S1980-993X20200002003102020-04-13Sorption of Remazol Black B dye in alluvial soils of the Capibaribe River Basin, Pernambuco, BrazilAlves,Adriana Thays AraújoSilva,Luisa Thaynara Muricy de SouzaAlcântara,Lucas Ravellys Pyrrho deBarros,Vitor Hugo de OliveiraSantos Neto,Severino Martins dosLima,Valmir Félix deLima,José Romualdo de SousaCoutinho,Artur PaivaAntonino,Antonio Celso Dantas isotherm kinetics mobility Abstract Wastewater from textile industries is loaded with synthetic dyes. These effluents are often not adequately treated, affecting the soil and groundwater quality and leading to environmental contamination. The Agreste mesoregion of the state of Pernambuco is home to one of the largest textile centers in Brazil. This work therefore aims to study the behavior of Remazol Black B (RB5) dye in subsurface mediums in this region. The kinetics and isotherm sorption experiments allowed an evaluation of RB5 retention capacity in two layers of alluvial soil of the dry riverbed of the Capibaribe Basin. The maximum sorption rate was 81.81 mg kg-1 and 21.7 mg kg-1 for the loamy sand and sand layers, respectively. The Pseudo-second order kinetic model described more appropriately the sorption kinetics for both soils. The isotherms behavior was nonlinear, and Freundlich model was the most suitable to describe this process for both soils, presenting KF values of 8.6407 L kg-1 for loamy sand and 0.1868 L kg-1 for sand. The isotherm parameters confirm a more significant interaction of RB5 with the loamy sand layer than with the sand layer, indicating lower leaching in the first layer, which is less mobile for RB5 contamination. Furthermore, the different sorption rates for both soils indicate the importance of studying the soil as a heterogeneous profile.info:eu-repo/semantics/openAccessInstituto de Pesquisas Ambientais em Bacias HidrográficasRevista Ambiente & Água v.15 n.2 20202020-01-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1980-993X2020000200310en10.4136/ambi-agua.2491
institution SCIELO
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country Brasil
countrycode BR
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libraryname SciELO
language English
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author Alves,Adriana Thays Araújo
Silva,Luisa Thaynara Muricy de Souza
Alcântara,Lucas Ravellys Pyrrho de
Barros,Vitor Hugo de Oliveira
Santos Neto,Severino Martins dos
Lima,Valmir Félix de
Lima,José Romualdo de Sousa
Coutinho,Artur Paiva
Antonino,Antonio Celso Dantas
spellingShingle Alves,Adriana Thays Araújo
Silva,Luisa Thaynara Muricy de Souza
Alcântara,Lucas Ravellys Pyrrho de
Barros,Vitor Hugo de Oliveira
Santos Neto,Severino Martins dos
Lima,Valmir Félix de
Lima,José Romualdo de Sousa
Coutinho,Artur Paiva
Antonino,Antonio Celso Dantas
Sorption of Remazol Black B dye in alluvial soils of the Capibaribe River Basin, Pernambuco, Brazil
author_facet Alves,Adriana Thays Araújo
Silva,Luisa Thaynara Muricy de Souza
Alcântara,Lucas Ravellys Pyrrho de
Barros,Vitor Hugo de Oliveira
Santos Neto,Severino Martins dos
Lima,Valmir Félix de
Lima,José Romualdo de Sousa
Coutinho,Artur Paiva
Antonino,Antonio Celso Dantas
author_sort Alves,Adriana Thays Araújo
title Sorption of Remazol Black B dye in alluvial soils of the Capibaribe River Basin, Pernambuco, Brazil
title_short Sorption of Remazol Black B dye in alluvial soils of the Capibaribe River Basin, Pernambuco, Brazil
title_full Sorption of Remazol Black B dye in alluvial soils of the Capibaribe River Basin, Pernambuco, Brazil
title_fullStr Sorption of Remazol Black B dye in alluvial soils of the Capibaribe River Basin, Pernambuco, Brazil
title_full_unstemmed Sorption of Remazol Black B dye in alluvial soils of the Capibaribe River Basin, Pernambuco, Brazil
title_sort sorption of remazol black b dye in alluvial soils of the capibaribe river basin, pernambuco, brazil
description Abstract Wastewater from textile industries is loaded with synthetic dyes. These effluents are often not adequately treated, affecting the soil and groundwater quality and leading to environmental contamination. The Agreste mesoregion of the state of Pernambuco is home to one of the largest textile centers in Brazil. This work therefore aims to study the behavior of Remazol Black B (RB5) dye in subsurface mediums in this region. The kinetics and isotherm sorption experiments allowed an evaluation of RB5 retention capacity in two layers of alluvial soil of the dry riverbed of the Capibaribe Basin. The maximum sorption rate was 81.81 mg kg-1 and 21.7 mg kg-1 for the loamy sand and sand layers, respectively. The Pseudo-second order kinetic model described more appropriately the sorption kinetics for both soils. The isotherms behavior was nonlinear, and Freundlich model was the most suitable to describe this process for both soils, presenting KF values of 8.6407 L kg-1 for loamy sand and 0.1868 L kg-1 for sand. The isotherm parameters confirm a more significant interaction of RB5 with the loamy sand layer than with the sand layer, indicating lower leaching in the first layer, which is less mobile for RB5 contamination. Furthermore, the different sorption rates for both soils indicate the importance of studying the soil as a heterogeneous profile.
publisher Instituto de Pesquisas Ambientais em Bacias Hidrográficas
publishDate 2020
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1980-993X2020000200310
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