An alternative description of aromaticity in metallabenzenes
Abstract. Experimental and theoretical studies of metallabenzenes have revealed important differences in their aromatic properties when compared with their organic analogs. In this work, an alternative explanation for this unconventional behavior is presented based on the idea that metallabenzenes can be conceived as an intermediate structure between the benzene and the benzenium ion; an idea derived from a critical analysis of the isolobal analogies in metallabenzenes.
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Sociedad Química de México A.C.
2017
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oai:scielo:S1870-249X20170002000972018-01-11An alternative description of aromaticity in metallabenzenesDávila,Kleyra L.Contreras,Ricardo R.Fontal,BernardoTorres,F. JavierRincón,Luis Metallabenzenes Isolobal Analogies Aromaticity Abstract. Experimental and theoretical studies of metallabenzenes have revealed important differences in their aromatic properties when compared with their organic analogs. In this work, an alternative explanation for this unconventional behavior is presented based on the idea that metallabenzenes can be conceived as an intermediate structure between the benzene and the benzenium ion; an idea derived from a critical analysis of the isolobal analogies in metallabenzenes.info:eu-repo/semantics/openAccessSociedad Química de México A.C.Journal of the Mexican Chemical Society v.61 n.2 20172017-06-01info:eu-repo/semantics/articletext/htmlhttp://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2017000200097en |
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English |
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| author |
Dávila,Kleyra L. Contreras,Ricardo R. Fontal,Bernardo Torres,F. Javier Rincón,Luis |
| spellingShingle |
Dávila,Kleyra L. Contreras,Ricardo R. Fontal,Bernardo Torres,F. Javier Rincón,Luis An alternative description of aromaticity in metallabenzenes |
| author_facet |
Dávila,Kleyra L. Contreras,Ricardo R. Fontal,Bernardo Torres,F. Javier Rincón,Luis |
| author_sort |
Dávila,Kleyra L. |
| title |
An alternative description of aromaticity in metallabenzenes |
| title_short |
An alternative description of aromaticity in metallabenzenes |
| title_full |
An alternative description of aromaticity in metallabenzenes |
| title_fullStr |
An alternative description of aromaticity in metallabenzenes |
| title_full_unstemmed |
An alternative description of aromaticity in metallabenzenes |
| title_sort |
alternative description of aromaticity in metallabenzenes |
| description |
Abstract. Experimental and theoretical studies of metallabenzenes have revealed important differences in their aromatic properties when compared with their organic analogs. In this work, an alternative explanation for this unconventional behavior is presented based on the idea that metallabenzenes can be conceived as an intermediate structure between the benzene and the benzenium ion; an idea derived from a critical analysis of the isolobal analogies in metallabenzenes. |
| publisher |
Sociedad Química de México A.C. |
| publishDate |
2017 |
| url |
http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2017000200097 |
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