Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azides

Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azides

The synthesis of 1,4-disubstituted-1,2,3-triazoles from alkyl azides and terminal alkynes at room temperature and under microwave heating was attained using Cu(I), generated in-situ from copper(II) sulfate and phenylboronic acid, as catalyst. Twelve new triazoles were obtained in moderate to good yields (53-98%), and the products were obtained by crystallization from the mixture reaction without further purification.

Saved in:
Bibliographic Details
Main Authors: de la Cerda-Pedro,José Emilio, Rojas-Lima,Susana, Santillan,Rosa, López-Ruiz,Heraclio
Format: Digital revista
Language:English
Published: Sociedad Química de México A.C. 2015
Online Access:http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2015000200007
Tags: Add Tag
No Tags, Be the first to tag this record!
id oai:scielo:S1870-249X2015000200007
record_format ojs
spelling oai:scielo:S1870-249X20150002000072015-10-22Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azidesde la Cerda-Pedro,José EmilioRojas-Lima,SusanaSantillan,RosaLópez-Ruiz,Heraclio triazoles phenylboronic acid CuSO4 Microwave irradiation The synthesis of 1,4-disubstituted-1,2,3-triazoles from alkyl azides and terminal alkynes at room temperature and under microwave heating was attained using Cu(I), generated in-situ from copper(II) sulfate and phenylboronic acid, as catalyst. Twelve new triazoles were obtained in moderate to good yields (53-98%), and the products were obtained by crystallization from the mixture reaction without further purification.info:eu-repo/semantics/openAccessSociedad Química de México A.C.Journal of the Mexican Chemical Society v.59 n.2 20152015-06-01info:eu-repo/semantics/articletext/htmlhttp://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2015000200007en
institution SCIELO
collection OJS
country México
countrycode MX
component Revista
access En linea
databasecode rev-scielo-mx
tag revista
region America del Norte
libraryname SciELO
language English
format Digital
author de la Cerda-Pedro,José Emilio
Rojas-Lima,Susana
Santillan,Rosa
López-Ruiz,Heraclio
spellingShingle de la Cerda-Pedro,José Emilio
Rojas-Lima,Susana
Santillan,Rosa
López-Ruiz,Heraclio
Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azides
author_facet de la Cerda-Pedro,José Emilio
Rojas-Lima,Susana
Santillan,Rosa
López-Ruiz,Heraclio
author_sort de la Cerda-Pedro,José Emilio
title Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azides
title_short Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azides
title_full Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azides
title_fullStr Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azides
title_full_unstemmed Phenylboronic Acid/CuSO4 as an Efficient Catalyst for the Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Terminal Acetylenes and Alkyl Azides
title_sort phenylboronic acid/cuso4 as an efficient catalyst for the synthesis of 1,4-disubstituted-1,2,3-triazoles from terminal acetylenes and alkyl azides
description The synthesis of 1,4-disubstituted-1,2,3-triazoles from alkyl azides and terminal alkynes at room temperature and under microwave heating was attained using Cu(I), generated in-situ from copper(II) sulfate and phenylboronic acid, as catalyst. Twelve new triazoles were obtained in moderate to good yields (53-98%), and the products were obtained by crystallization from the mixture reaction without further purification.
publisher Sociedad Química de México A.C.
publishDate 2015
url http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2015000200007
work_keys_str_mv AT delacerdapedrojoseemilio phenylboronicacidcuso4asanefficientcatalystforthesynthesisof14disubstituted123triazolesfromterminalacetylenesandalkylazides
AT rojaslimasusana phenylboronicacidcuso4asanefficientcatalystforthesynthesisof14disubstituted123triazolesfromterminalacetylenesandalkylazides
AT santillanrosa phenylboronicacidcuso4asanefficientcatalystforthesynthesisof14disubstituted123triazolesfromterminalacetylenesandalkylazides
AT lopezruizheraclio phenylboronicacidcuso4asanefficientcatalystforthesynthesisof14disubstituted123triazolesfromterminalacetylenesandalkylazides
_version_ 1756228508061794305

Similar Items