Effect of Multiwalled Carbon Nanotubes on the Properties of PMMA/PEO Blends

Poly (methyl methacrylate) (PMMA)/Poly ethylene oxide (PEO) (15 wt.% PMMA/85 wt.% PEO (PMMA/PEO-A) and 30 wt.% PMMA/70 wt.% PEO (PMMA/PEO-B)) blends, and functionalized multiwalled carbon nanotubes (F-MWNTs) filled PMMA/PEO-A and PMMA/PEO-B composites were prepared via solution casting technique. The morphological study showed the formation of cracks in F-MWNTs/PMMA/PEO blend. The mechanical properties of PMMA/PEO blend were decrease by incorporation of F-MWNTs, which might be due to less compatibility between F-MWNTs and PMMA/PEO blends. Neat PEO upon crystallization showed distinct sized spherulites, which decreased by the incorporation o F-MWNTs (nucleation effect of FMWNTs). The X-ray diffraction (XRD) analyses revealed that the intensity of peaks decreased by incorporation of nanotubes, which means that the PEO crystallinity was suppressed in the presence of F-MWNTs. The thermal stabilities of PMMA/PEO blend were improved by incorporation of F-MWNTs.

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Main Authors: Saeed,Khalid, Khan,Nasib
Format: Digital revista
Language:English
Published: Sociedad Química de México A.C. 2014
Online Access:http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2014000100010
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spelling oai:scielo:S1870-249X20140001000102014-06-26Effect of Multiwalled Carbon Nanotubes on the Properties of PMMA/PEO BlendsSaeed,KhalidKhan,Nasib Polymer blends Multiwalled carbon nanotubes Composites spherulites Poly (methyl methacrylate) (PMMA)/Poly ethylene oxide (PEO) (15 wt.% PMMA/85 wt.% PEO (PMMA/PEO-A) and 30 wt.% PMMA/70 wt.% PEO (PMMA/PEO-B)) blends, and functionalized multiwalled carbon nanotubes (F-MWNTs) filled PMMA/PEO-A and PMMA/PEO-B composites were prepared via solution casting technique. The morphological study showed the formation of cracks in F-MWNTs/PMMA/PEO blend. The mechanical properties of PMMA/PEO blend were decrease by incorporation of F-MWNTs, which might be due to less compatibility between F-MWNTs and PMMA/PEO blends. Neat PEO upon crystallization showed distinct sized spherulites, which decreased by the incorporation o F-MWNTs (nucleation effect of FMWNTs). The X-ray diffraction (XRD) analyses revealed that the intensity of peaks decreased by incorporation of nanotubes, which means that the PEO crystallinity was suppressed in the presence of F-MWNTs. The thermal stabilities of PMMA/PEO blend were improved by incorporation of F-MWNTs.info:eu-repo/semantics/openAccessSociedad Química de México A.C.Journal of the Mexican Chemical Society v.58 n.1 20142014-03-01info:eu-repo/semantics/articletext/htmlhttp://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2014000100010en
institution SCIELO
collection OJS
country México
countrycode MX
component Revista
access En linea
databasecode rev-scielo-mx
tag revista
region America del Norte
libraryname SciELO
language English
format Digital
author Saeed,Khalid
Khan,Nasib
spellingShingle Saeed,Khalid
Khan,Nasib
Effect of Multiwalled Carbon Nanotubes on the Properties of PMMA/PEO Blends
author_facet Saeed,Khalid
Khan,Nasib
author_sort Saeed,Khalid
title Effect of Multiwalled Carbon Nanotubes on the Properties of PMMA/PEO Blends
title_short Effect of Multiwalled Carbon Nanotubes on the Properties of PMMA/PEO Blends
title_full Effect of Multiwalled Carbon Nanotubes on the Properties of PMMA/PEO Blends
title_fullStr Effect of Multiwalled Carbon Nanotubes on the Properties of PMMA/PEO Blends
title_full_unstemmed Effect of Multiwalled Carbon Nanotubes on the Properties of PMMA/PEO Blends
title_sort effect of multiwalled carbon nanotubes on the properties of pmma/peo blends
description Poly (methyl methacrylate) (PMMA)/Poly ethylene oxide (PEO) (15 wt.% PMMA/85 wt.% PEO (PMMA/PEO-A) and 30 wt.% PMMA/70 wt.% PEO (PMMA/PEO-B)) blends, and functionalized multiwalled carbon nanotubes (F-MWNTs) filled PMMA/PEO-A and PMMA/PEO-B composites were prepared via solution casting technique. The morphological study showed the formation of cracks in F-MWNTs/PMMA/PEO blend. The mechanical properties of PMMA/PEO blend were decrease by incorporation of F-MWNTs, which might be due to less compatibility between F-MWNTs and PMMA/PEO blends. Neat PEO upon crystallization showed distinct sized spherulites, which decreased by the incorporation o F-MWNTs (nucleation effect of FMWNTs). The X-ray diffraction (XRD) analyses revealed that the intensity of peaks decreased by incorporation of nanotubes, which means that the PEO crystallinity was suppressed in the presence of F-MWNTs. The thermal stabilities of PMMA/PEO blend were improved by incorporation of F-MWNTs.
publisher Sociedad Química de México A.C.
publishDate 2014
url http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2014000100010
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