Synthesis and Hydrolysis Monitoring of Sasrin-like Resin Bound Imines by Fluorescence Spectroscopy
Merrifield resin was converted to various dialkyl-trihy-droxybenzaldehyde resins and then to different bound imine resins. Fluorescence spectroscopy was used to continuously monitor the intermediates performed on the resins. Using fluorescent label (dansyl chloride) information on the kinetics of the amine cleavage was obtained. This study demonstrated that direct measures of fluorescence intensity on single-resin beads can be an effective method of monitoring solid phase organic reactions.
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Sociedad Química de México A.C.
2006
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oai:scielo:S1870-249X20060004000062016-11-16Synthesis and Hydrolysis Monitoring of Sasrin-like Resin Bound Imines by Fluorescence SpectroscopyMadrigal,DomingoPina-Luis,GeorginaRivero,Ignacio A. Fluorescence spectroscopy monitoring reaction solid phase Merrifield resin was converted to various dialkyl-trihy-droxybenzaldehyde resins and then to different bound imine resins. Fluorescence spectroscopy was used to continuously monitor the intermediates performed on the resins. Using fluorescent label (dansyl chloride) information on the kinetics of the amine cleavage was obtained. This study demonstrated that direct measures of fluorescence intensity on single-resin beads can be an effective method of monitoring solid phase organic reactions.info:eu-repo/semantics/openAccessSociedad Química de México A.C.Journal of the Mexican Chemical Society v.50 n.4 20062006-12-01info:eu-repo/semantics/articletext/htmlhttp://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2006000400006en |
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MX |
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English |
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| author |
Madrigal,Domingo Pina-Luis,Georgina Rivero,Ignacio A. |
| spellingShingle |
Madrigal,Domingo Pina-Luis,Georgina Rivero,Ignacio A. Synthesis and Hydrolysis Monitoring of Sasrin-like Resin Bound Imines by Fluorescence Spectroscopy |
| author_facet |
Madrigal,Domingo Pina-Luis,Georgina Rivero,Ignacio A. |
| author_sort |
Madrigal,Domingo |
| title |
Synthesis and Hydrolysis Monitoring of Sasrin-like Resin Bound Imines by Fluorescence Spectroscopy |
| title_short |
Synthesis and Hydrolysis Monitoring of Sasrin-like Resin Bound Imines by Fluorescence Spectroscopy |
| title_full |
Synthesis and Hydrolysis Monitoring of Sasrin-like Resin Bound Imines by Fluorescence Spectroscopy |
| title_fullStr |
Synthesis and Hydrolysis Monitoring of Sasrin-like Resin Bound Imines by Fluorescence Spectroscopy |
| title_full_unstemmed |
Synthesis and Hydrolysis Monitoring of Sasrin-like Resin Bound Imines by Fluorescence Spectroscopy |
| title_sort |
synthesis and hydrolysis monitoring of sasrin-like resin bound imines by fluorescence spectroscopy |
| description |
Merrifield resin was converted to various dialkyl-trihy-droxybenzaldehyde resins and then to different bound imine resins. Fluorescence spectroscopy was used to continuously monitor the intermediates performed on the resins. Using fluorescent label (dansyl chloride) information on the kinetics of the amine cleavage was obtained. This study demonstrated that direct measures of fluorescence intensity on single-resin beads can be an effective method of monitoring solid phase organic reactions. |
| publisher |
Sociedad Química de México A.C. |
| publishDate |
2006 |
| url |
http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2006000400006 |
| work_keys_str_mv |
AT madrigaldomingo synthesisandhydrolysismonitoringofsasrinlikeresinboundiminesbyfluorescencespectroscopy AT pinaluisgeorgina synthesisandhydrolysismonitoringofsasrinlikeresinboundiminesbyfluorescencespectroscopy AT riveroignacioa synthesisandhydrolysismonitoringofsasrinlikeresinboundiminesbyfluorescencespectroscopy |
| _version_ |
1756228451988144128 |