Characterization of biochars from different sources and evaluation of release of nutrients and contaminants

ABSTRACT The biochar, product of pyrolysis of organic waste, has been used as a soil conditioner and alternative on solid waste management. However, the raw material and pyrolysis temperature used influence the quantity and dynamics of release of nutrients and contaminants from the biochar. The objective was to evaluate the use of waste sugarcane bagasse, eucalyptus and sewage sludge for production of biochar and determine the chemical, physical, mineralogical properties and acid extraction of these materials produced at 350 °C and 500 °C. Were evaluated the proportion of C, H, N, O; ashes; macro and micronutrients, plus some contaminants; characterization of mineral phases by diffractometry of X- rays; functional groups by infrared absorption spectroscopy (FTIR). Moreover, it was determined the release of nutrients and contaminants for the extraction in increasing concentration of HNO3 (0,01 - 2,0 mol L-1). The O/C and H/C relations decreased with increasing temperature of pyrolysis, which define a greater stability of the C of biochars. Sewage sludge biochar (BC-L) had the highest nutrient release rates and contaminant metals (Cd, Cr, Ni and Pb). Acid extraction of other biochars was very low (<20% of the total content). The results indicate that the carbon fraction of biochar contributes to the low rate of release of the elements in acid place.

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Main Authors: Figueredo,Natália Aragão de, Costa,Liovando Marciano da, Melo,Leônidas Carrijo Azevedo, Siebeneichlerd,Evair Antônio, Tronto,Jairo
Format: Digital revista
Language:English
Published: Universidade Federal do Ceará 2017
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1806-66902017000300003
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spelling oai:scielo:S1806-669020170003000032017-05-22Characterization of biochars from different sources and evaluation of release of nutrients and contaminantsFigueredo,Natália Aragão deCosta,Liovando Marciano daMelo,Leônidas Carrijo AzevedoSiebeneichlerd,Evair AntônioTronto,Jairo Biochar Waste Acid extraction ABSTRACT The biochar, product of pyrolysis of organic waste, has been used as a soil conditioner and alternative on solid waste management. However, the raw material and pyrolysis temperature used influence the quantity and dynamics of release of nutrients and contaminants from the biochar. The objective was to evaluate the use of waste sugarcane bagasse, eucalyptus and sewage sludge for production of biochar and determine the chemical, physical, mineralogical properties and acid extraction of these materials produced at 350 °C and 500 °C. Were evaluated the proportion of C, H, N, O; ashes; macro and micronutrients, plus some contaminants; characterization of mineral phases by diffractometry of X- rays; functional groups by infrared absorption spectroscopy (FTIR). Moreover, it was determined the release of nutrients and contaminants for the extraction in increasing concentration of HNO3 (0,01 - 2,0 mol L-1). The O/C and H/C relations decreased with increasing temperature of pyrolysis, which define a greater stability of the C of biochars. Sewage sludge biochar (BC-L) had the highest nutrient release rates and contaminant metals (Cd, Cr, Ni and Pb). Acid extraction of other biochars was very low (<20% of the total content). The results indicate that the carbon fraction of biochar contributes to the low rate of release of the elements in acid place.info:eu-repo/semantics/openAccessUniversidade Federal do CearáRevista Ciência Agronômica v.48 n.3 20172017-07-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1806-66902017000300003en10.5935/1806-6690.20170046
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country Brasil
countrycode BR
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libraryname SciELO
language English
format Digital
author Figueredo,Natália Aragão de
Costa,Liovando Marciano da
Melo,Leônidas Carrijo Azevedo
Siebeneichlerd,Evair Antônio
Tronto,Jairo
spellingShingle Figueredo,Natália Aragão de
Costa,Liovando Marciano da
Melo,Leônidas Carrijo Azevedo
Siebeneichlerd,Evair Antônio
Tronto,Jairo
Characterization of biochars from different sources and evaluation of release of nutrients and contaminants
author_facet Figueredo,Natália Aragão de
Costa,Liovando Marciano da
Melo,Leônidas Carrijo Azevedo
Siebeneichlerd,Evair Antônio
Tronto,Jairo
author_sort Figueredo,Natália Aragão de
title Characterization of biochars from different sources and evaluation of release of nutrients and contaminants
title_short Characterization of biochars from different sources and evaluation of release of nutrients and contaminants
title_full Characterization of biochars from different sources and evaluation of release of nutrients and contaminants
title_fullStr Characterization of biochars from different sources and evaluation of release of nutrients and contaminants
title_full_unstemmed Characterization of biochars from different sources and evaluation of release of nutrients and contaminants
title_sort characterization of biochars from different sources and evaluation of release of nutrients and contaminants
description ABSTRACT The biochar, product of pyrolysis of organic waste, has been used as a soil conditioner and alternative on solid waste management. However, the raw material and pyrolysis temperature used influence the quantity and dynamics of release of nutrients and contaminants from the biochar. The objective was to evaluate the use of waste sugarcane bagasse, eucalyptus and sewage sludge for production of biochar and determine the chemical, physical, mineralogical properties and acid extraction of these materials produced at 350 °C and 500 °C. Were evaluated the proportion of C, H, N, O; ashes; macro and micronutrients, plus some contaminants; characterization of mineral phases by diffractometry of X- rays; functional groups by infrared absorption spectroscopy (FTIR). Moreover, it was determined the release of nutrients and contaminants for the extraction in increasing concentration of HNO3 (0,01 - 2,0 mol L-1). The O/C and H/C relations decreased with increasing temperature of pyrolysis, which define a greater stability of the C of biochars. Sewage sludge biochar (BC-L) had the highest nutrient release rates and contaminant metals (Cd, Cr, Ni and Pb). Acid extraction of other biochars was very low (<20% of the total content). The results indicate that the carbon fraction of biochar contributes to the low rate of release of the elements in acid place.
publisher Universidade Federal do Ceará
publishDate 2017
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1806-66902017000300003
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