Evaluation of Corrosion Resistance of Commercial Aluminum Alloys in Ethanol Solutions

In the present research, we studied the corrosion resistance of commercial aluminum alloys exposed to ethanol produced in the northeastern region of Argentina and to commercial ethanol as reference medium. Electrochemical tests of potentiodynamic polarization and weight loss were performed by immersion at temperatures below the boiling point of ethanol (25 °C, 40 °C and 50 °C). The results showed that the increase in the corrosion rate of the alloys is directly proportional to the increase in the temperature of the solution, and that the combined action of contaminants in the alcohol (water, organic acids or aggressive ions) contributed to the increase in the aggressiveness of the environment. Specifically, through the results of the gravimetric tests, corrosion products characteristic of the formation of pitting corrosion and alkoxidation were observed. In contrast to the above, the existence of the pitting corrosion mechanism was demonstrated by defining a pitting potential in the potentiodynamic polarization curves.

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Main Authors: Kramer,Gustavo Raúl, Méndez,Claudia Marcela, Ares,Alicia Esther
Format: Digital revista
Language:English
Published: ABM, ABC, ABPol 2018
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000600233
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spelling oai:scielo:S1516-143920180006002332018-10-19Evaluation of Corrosion Resistance of Commercial Aluminum Alloys in Ethanol SolutionsKramer,Gustavo RaúlMéndez,Claudia MarcelaAres,Alicia Esther corrosion aluminum alloys ethanol In the present research, we studied the corrosion resistance of commercial aluminum alloys exposed to ethanol produced in the northeastern region of Argentina and to commercial ethanol as reference medium. Electrochemical tests of potentiodynamic polarization and weight loss were performed by immersion at temperatures below the boiling point of ethanol (25 °C, 40 °C and 50 °C). The results showed that the increase in the corrosion rate of the alloys is directly proportional to the increase in the temperature of the solution, and that the combined action of contaminants in the alcohol (water, organic acids or aggressive ions) contributed to the increase in the aggressiveness of the environment. Specifically, through the results of the gravimetric tests, corrosion products characteristic of the formation of pitting corrosion and alkoxidation were observed. In contrast to the above, the existence of the pitting corrosion mechanism was demonstrated by defining a pitting potential in the potentiodynamic polarization curves.info:eu-repo/semantics/openAccessABM, ABC, ABPolMaterials Research v.21 n.6 20182018-01-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000600233en10.1590/1980-5373-mr-2017-0272
institution SCIELO
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country Brasil
countrycode BR
component Revista
access En linea
databasecode rev-scielo-br
tag revista
region America del Sur
libraryname SciELO
language English
format Digital
author Kramer,Gustavo Raúl
Méndez,Claudia Marcela
Ares,Alicia Esther
spellingShingle Kramer,Gustavo Raúl
Méndez,Claudia Marcela
Ares,Alicia Esther
Evaluation of Corrosion Resistance of Commercial Aluminum Alloys in Ethanol Solutions
author_facet Kramer,Gustavo Raúl
Méndez,Claudia Marcela
Ares,Alicia Esther
author_sort Kramer,Gustavo Raúl
title Evaluation of Corrosion Resistance of Commercial Aluminum Alloys in Ethanol Solutions
title_short Evaluation of Corrosion Resistance of Commercial Aluminum Alloys in Ethanol Solutions
title_full Evaluation of Corrosion Resistance of Commercial Aluminum Alloys in Ethanol Solutions
title_fullStr Evaluation of Corrosion Resistance of Commercial Aluminum Alloys in Ethanol Solutions
title_full_unstemmed Evaluation of Corrosion Resistance of Commercial Aluminum Alloys in Ethanol Solutions
title_sort evaluation of corrosion resistance of commercial aluminum alloys in ethanol solutions
description In the present research, we studied the corrosion resistance of commercial aluminum alloys exposed to ethanol produced in the northeastern region of Argentina and to commercial ethanol as reference medium. Electrochemical tests of potentiodynamic polarization and weight loss were performed by immersion at temperatures below the boiling point of ethanol (25 °C, 40 °C and 50 °C). The results showed that the increase in the corrosion rate of the alloys is directly proportional to the increase in the temperature of the solution, and that the combined action of contaminants in the alcohol (water, organic acids or aggressive ions) contributed to the increase in the aggressiveness of the environment. Specifically, through the results of the gravimetric tests, corrosion products characteristic of the formation of pitting corrosion and alkoxidation were observed. In contrast to the above, the existence of the pitting corrosion mechanism was demonstrated by defining a pitting potential in the potentiodynamic polarization curves.
publisher ABM, ABC, ABPol
publishDate 2018
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000600233
work_keys_str_mv AT kramergustavoraul evaluationofcorrosionresistanceofcommercialaluminumalloysinethanolsolutions
AT mendezclaudiamarcela evaluationofcorrosionresistanceofcommercialaluminumalloysinethanolsolutions
AT aresaliciaesther evaluationofcorrosionresistanceofcommercialaluminumalloysinethanolsolutions
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