Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites
Ceramic matrix composites (CMCs), constituted of a silicon boron oxycarbide (SiBCO) matrix and unidirectional carbon fiber rods as a reinforcement phase, were prepared by pyrolysis of carbon fiber rods wrapped in polysiloxane (PS) or poly(borosiloxane) (PBS) matrices. The preparation of the polymeric precursors involved hydrolysis/condensation reactions of alkoxysilanes in the presence and absence of boric acid, with B/Si atomic ratios of 0.2 and 0.5. Infrared spectra of PBS showed evidence of Si-O-B bonds at 880 cm-1, due to the incorporation of the crosslinker trigonal units of BO3 in the polymeric network. X ray diffraction analyses exhibited an amorphous character of the resulting polymer-derived ceramics obtained by pyrolysis up to 1000 °C under inert atmosphere. The C/SiBCO composites showed better thermal stability than the C/SiOC materials. In addition, good adhesion between the carbon fiber and the ceramic phase was observed by SEM microscopy
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2007
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oai:scielo:S1516-143920070002000092007-09-04Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix compositesSiqueira,Renato LuizYoshida,Inez Valéria PagottoPardini,Luiz ClaudioSchiavon,Marco Antônio precursors poly(borosiloxanes) carbon fibers composites Ceramic matrix composites (CMCs), constituted of a silicon boron oxycarbide (SiBCO) matrix and unidirectional carbon fiber rods as a reinforcement phase, were prepared by pyrolysis of carbon fiber rods wrapped in polysiloxane (PS) or poly(borosiloxane) (PBS) matrices. The preparation of the polymeric precursors involved hydrolysis/condensation reactions of alkoxysilanes in the presence and absence of boric acid, with B/Si atomic ratios of 0.2 and 0.5. Infrared spectra of PBS showed evidence of Si-O-B bonds at 880 cm-1, due to the incorporation of the crosslinker trigonal units of BO3 in the polymeric network. X ray diffraction analyses exhibited an amorphous character of the resulting polymer-derived ceramics obtained by pyrolysis up to 1000 °C under inert atmosphere. The C/SiBCO composites showed better thermal stability than the C/SiOC materials. In addition, good adhesion between the carbon fiber and the ceramic phase was observed by SEM microscopyinfo:eu-repo/semantics/openAccessABM, ABC, ABPolMaterials Research v.10 n.2 20072007-06-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000200009en10.1590/S1516-14392007000200009 |
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Siqueira,Renato Luiz Yoshida,Inez Valéria Pagotto Pardini,Luiz Claudio Schiavon,Marco Antônio |
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Siqueira,Renato Luiz Yoshida,Inez Valéria Pagotto Pardini,Luiz Claudio Schiavon,Marco Antônio Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites |
author_facet |
Siqueira,Renato Luiz Yoshida,Inez Valéria Pagotto Pardini,Luiz Claudio Schiavon,Marco Antônio |
author_sort |
Siqueira,Renato Luiz |
title |
Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites |
title_short |
Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites |
title_full |
Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites |
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Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites |
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Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites |
title_sort |
poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites |
description |
Ceramic matrix composites (CMCs), constituted of a silicon boron oxycarbide (SiBCO) matrix and unidirectional carbon fiber rods as a reinforcement phase, were prepared by pyrolysis of carbon fiber rods wrapped in polysiloxane (PS) or poly(borosiloxane) (PBS) matrices. The preparation of the polymeric precursors involved hydrolysis/condensation reactions of alkoxysilanes in the presence and absence of boric acid, with B/Si atomic ratios of 0.2 and 0.5. Infrared spectra of PBS showed evidence of Si-O-B bonds at 880 cm-1, due to the incorporation of the crosslinker trigonal units of BO3 in the polymeric network. X ray diffraction analyses exhibited an amorphous character of the resulting polymer-derived ceramics obtained by pyrolysis up to 1000 °C under inert atmosphere. The C/SiBCO composites showed better thermal stability than the C/SiOC materials. In addition, good adhesion between the carbon fiber and the ceramic phase was observed by SEM microscopy |
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ABM, ABC, ABPol |
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2007 |
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http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000200009 |
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AT siqueirarenatoluiz polyborosiloxanesasprecursorsforcarbonfiberceramicmatrixcomposites AT yoshidainezvaleriapagotto polyborosiloxanesasprecursorsforcarbonfiberceramicmatrixcomposites AT pardiniluizclaudio polyborosiloxanesasprecursorsforcarbonfiberceramicmatrixcomposites AT schiavonmarcoantonio polyborosiloxanesasprecursorsforcarbonfiberceramicmatrixcomposites |
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