Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp

ABSTRACT The objectives of this study were to fit mathematical models to the experimental data of the drying of the pequi mesocarp, determine the effective diffusion coefficient, and to obtain activation energy and thermodynamic and nutritional properties in different drying conditions. The mesocarp of pequi fruits, with an initial moisture content of 5.05 (decimal, dry basis), was dried in a forced ventilation oven at temperatures of 40, 50, 60 and 70 °C until the final moisture content of 0.15 ± 0.01 (decimal, dry basis). The mathematical models were adjusted by non-linear regression analysis using the Gauss-Newton method, considering the magnitude of the coefficient of determination (R2), the mean relative error (P) and the estimated mean error (SE). Among the models analyzed, the Midilli model presented the best fit. The effective diffusion coefficient increased with increase in temperature, and the activation energy on drying was 11.011 kJ mol-1. The enthalpy decreased with an increase in the drying temperature, while the entropy and Gibbs free energy increased with the drying temperature. The product obtained from drying has low lipid and high carbohydrate concentration, while temperatures above 70 °C could cause denaturation and/or protein complexation. The temperature of 60 °C is most suitable to obtain flour of pequi mesocarp, due to the shorter processing time while maintaining the nutritional quality.

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Main Authors: Souza,Jéssica L. F., Oliveira,Daniel E. C., Plácido,Geovana R., Egea,Mariana B., Caliari,Márcio, Silva,Marco A. P. da
Format: Digital revista
Language:English
Published: Departamento de Engenharia Agrícola - UFCG 2019
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662019000900655
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spelling oai:scielo:S1415-436620190009006552019-08-08Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarpSouza,Jéssica L. F.Oliveira,Daniel E. C.Plácido,Geovana R.Egea,Mariana B.Caliari,MárcioSilva,Marco A. P. da mathematical modeling activation energy Midilli model by-product utilization ABSTRACT The objectives of this study were to fit mathematical models to the experimental data of the drying of the pequi mesocarp, determine the effective diffusion coefficient, and to obtain activation energy and thermodynamic and nutritional properties in different drying conditions. The mesocarp of pequi fruits, with an initial moisture content of 5.05 (decimal, dry basis), was dried in a forced ventilation oven at temperatures of 40, 50, 60 and 70 °C until the final moisture content of 0.15 ± 0.01 (decimal, dry basis). The mathematical models were adjusted by non-linear regression analysis using the Gauss-Newton method, considering the magnitude of the coefficient of determination (R2), the mean relative error (P) and the estimated mean error (SE). Among the models analyzed, the Midilli model presented the best fit. The effective diffusion coefficient increased with increase in temperature, and the activation energy on drying was 11.011 kJ mol-1. The enthalpy decreased with an increase in the drying temperature, while the entropy and Gibbs free energy increased with the drying temperature. The product obtained from drying has low lipid and high carbohydrate concentration, while temperatures above 70 °C could cause denaturation and/or protein complexation. The temperature of 60 °C is most suitable to obtain flour of pequi mesocarp, due to the shorter processing time while maintaining the nutritional quality.info:eu-repo/semantics/openAccessDepartamento de Engenharia Agrícola - UFCGRevista Brasileira de Engenharia Agrícola e Ambiental v.23 n.9 20192019-09-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662019000900655en10.1590/1807-1929/agriambi.v23n9p655-661
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country Brasil
countrycode BR
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libraryname SciELO
language English
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author Souza,Jéssica L. F.
Oliveira,Daniel E. C.
Plácido,Geovana R.
Egea,Mariana B.
Caliari,Márcio
Silva,Marco A. P. da
spellingShingle Souza,Jéssica L. F.
Oliveira,Daniel E. C.
Plácido,Geovana R.
Egea,Mariana B.
Caliari,Márcio
Silva,Marco A. P. da
Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
author_facet Souza,Jéssica L. F.
Oliveira,Daniel E. C.
Plácido,Geovana R.
Egea,Mariana B.
Caliari,Márcio
Silva,Marco A. P. da
author_sort Souza,Jéssica L. F.
title Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_short Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_full Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_fullStr Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_full_unstemmed Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_sort thermodynamic and nutritional properties and drying kinetics of pequi (caryocar brasiliense cambess) mesocarp
description ABSTRACT The objectives of this study were to fit mathematical models to the experimental data of the drying of the pequi mesocarp, determine the effective diffusion coefficient, and to obtain activation energy and thermodynamic and nutritional properties in different drying conditions. The mesocarp of pequi fruits, with an initial moisture content of 5.05 (decimal, dry basis), was dried in a forced ventilation oven at temperatures of 40, 50, 60 and 70 °C until the final moisture content of 0.15 ± 0.01 (decimal, dry basis). The mathematical models were adjusted by non-linear regression analysis using the Gauss-Newton method, considering the magnitude of the coefficient of determination (R2), the mean relative error (P) and the estimated mean error (SE). Among the models analyzed, the Midilli model presented the best fit. The effective diffusion coefficient increased with increase in temperature, and the activation energy on drying was 11.011 kJ mol-1. The enthalpy decreased with an increase in the drying temperature, while the entropy and Gibbs free energy increased with the drying temperature. The product obtained from drying has low lipid and high carbohydrate concentration, while temperatures above 70 °C could cause denaturation and/or protein complexation. The temperature of 60 °C is most suitable to obtain flour of pequi mesocarp, due to the shorter processing time while maintaining the nutritional quality.
publisher Departamento de Engenharia Agrícola - UFCG
publishDate 2019
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662019000900655
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