Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4

Inhibitive and adsorption properties of ethanol extract of vernonia amygdalina for the corrosion of mild steel were studied using weight loss, thermometric, gasometric and IR methods of monitoring corrosion. The results revealed that ethanol extract of Vernonia amygdalina inhibited the corrosion of mild steel. The inhibition efficiency of the extract increased as the concentration of the extract increases. The inhibitor was found to function by being adsorbed on the surface of mild steel. The adsorption of the inhibitor followed the Langmuir adsorption isotherm. IR spectra of the corrosion product (without inhibitor), the extract and the corrosion product (with the inhibitor) confirmed that ethanol extract of vernonia amygdalina is an adsorption inhibitor. Phytochemical studies also revealed that ethanol vernonia amygdalina contains tannin, saponnins, flavanoid and anthraquinone, all of them contributing to the corrosion inhibition. Physical adsorption mechanism has been proposed from the values of some of the thermodynamic parameters obtained.

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Main Authors: Odiongenyi,A.O., Odoemelam,S.A., Eddy,N.O.
Format: Digital revista
Language:English
Published: Sociedade Portuguesa de Electroquímica 2009
Online Access:http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004
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spelling oai:scielo:S0872-190420090001000042009-05-21Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4Odiongenyi,A.O.Odoemelam,S.A.Eddy,N.O. corrosion inhibition mild steel adsorption vernonia amygdalina Inhibitive and adsorption properties of ethanol extract of vernonia amygdalina for the corrosion of mild steel were studied using weight loss, thermometric, gasometric and IR methods of monitoring corrosion. The results revealed that ethanol extract of Vernonia amygdalina inhibited the corrosion of mild steel. The inhibition efficiency of the extract increased as the concentration of the extract increases. The inhibitor was found to function by being adsorbed on the surface of mild steel. The adsorption of the inhibitor followed the Langmuir adsorption isotherm. IR spectra of the corrosion product (without inhibitor), the extract and the corrosion product (with the inhibitor) confirmed that ethanol extract of vernonia amygdalina is an adsorption inhibitor. Phytochemical studies also revealed that ethanol vernonia amygdalina contains tannin, saponnins, flavanoid and anthraquinone, all of them contributing to the corrosion inhibition. Physical adsorption mechanism has been proposed from the values of some of the thermodynamic parameters obtained.info:eu-repo/semantics/openAccessSociedade Portuguesa de ElectroquímicaPortugaliae Electrochimica Acta v.27 n.1 20092009-01-01info:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004en
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country Portugal
countrycode PT
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region Europa del Sur
libraryname SciELO
language English
format Digital
author Odiongenyi,A.O.
Odoemelam,S.A.
Eddy,N.O.
spellingShingle Odiongenyi,A.O.
Odoemelam,S.A.
Eddy,N.O.
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4
author_facet Odiongenyi,A.O.
Odoemelam,S.A.
Eddy,N.O.
author_sort Odiongenyi,A.O.
title Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4
title_short Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4
title_full Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4
title_fullStr Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4
title_full_unstemmed Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4
title_sort corrosion inhibition and adsorption properties of ethanol extract of vernonia amygdalina for the corrosion of mild steel in h2so4
description Inhibitive and adsorption properties of ethanol extract of vernonia amygdalina for the corrosion of mild steel were studied using weight loss, thermometric, gasometric and IR methods of monitoring corrosion. The results revealed that ethanol extract of Vernonia amygdalina inhibited the corrosion of mild steel. The inhibition efficiency of the extract increased as the concentration of the extract increases. The inhibitor was found to function by being adsorbed on the surface of mild steel. The adsorption of the inhibitor followed the Langmuir adsorption isotherm. IR spectra of the corrosion product (without inhibitor), the extract and the corrosion product (with the inhibitor) confirmed that ethanol extract of vernonia amygdalina is an adsorption inhibitor. Phytochemical studies also revealed that ethanol vernonia amygdalina contains tannin, saponnins, flavanoid and anthraquinone, all of them contributing to the corrosion inhibition. Physical adsorption mechanism has been proposed from the values of some of the thermodynamic parameters obtained.
publisher Sociedade Portuguesa de Electroquímica
publishDate 2009
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004
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