Methanol Electrooxidation on Pt-Ru Catalysts Dispersed in Conducting Polyaniline Films

Methanol electrooxidation was investigated on tailored Pt-Ru-polyaniline catalysts prepared applying dynamic potential routines. The electrodes characterized by SEM, EDX and TEM present a uniform distribution of metal particles about 100 nm in size, composed of Ru and Pt on the fibrous polymer matrix. The effect of concentration in the range 0.05-1 M and temperature in the range 20 to 60 ºC on the methanol electrooxidation rate was determined. The apparent activation energy depends on the catalyst Ru content.

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Bibliographic Details
Main Authors: Kessler,T., Castro Luna,A.M., Triaca,W.E.
Format: Digital revista
Language:English
Published: Sociedade Portuguesa de Electroquímica 2004
Online Access:http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042004000400005
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