Electrochemical Study of Nickel (salen) and Cobalt (salen) Derivative Complexes in the Presence of Unsaturated Halides

The electrochemical intramolecular cyclisation of allyl 2-bromophenyl ethers in N,N'-dimethylformamide at constant current in a diaphragmless cell has been developed using Ni(II) and Co(II) complexes as electron-transfer mediators. Cyclic compounds are obtained in good yields under appropriate experimental conditions.

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Main Authors: Duñach,E., Esteves,A.P., Leite,L.F.M., Lemos,M.A., Medeiros,M.J., Olivero,S.
Format: Digital revista
Language:English
Published: Sociedade Portuguesa de Electroquímica 2003
Online Access:http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042003000200007
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spelling oai:scielo:S0872-190420030002000072009-01-21Electrochemical Study of Nickel (salen) and Cobalt (salen) Derivative Complexes in the Presence of Unsaturated HalidesDuñach,E.Esteves,A.P.Leite,L.F.M.Lemos,M.A.Medeiros,M.J.Olivero,S. electron transfer cyclisation nickel cobalt radicals heterocycles The electrochemical intramolecular cyclisation of allyl 2-bromophenyl ethers in N,N'-dimethylformamide at constant current in a diaphragmless cell has been developed using Ni(II) and Co(II) complexes as electron-transfer mediators. Cyclic compounds are obtained in good yields under appropriate experimental conditions.info:eu-repo/semantics/openAccessSociedade Portuguesa de ElectroquímicaPortugaliae Electrochimica Acta v.21 n.2 20032003-01-01info:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042003000200007en
institution SCIELO
collection OJS
country Portugal
countrycode PT
component Revista
access En linea
databasecode rev-scielo-pt
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region Europa del Sur
libraryname SciELO
language English
format Digital
author Duñach,E.
Esteves,A.P.
Leite,L.F.M.
Lemos,M.A.
Medeiros,M.J.
Olivero,S.
spellingShingle Duñach,E.
Esteves,A.P.
Leite,L.F.M.
Lemos,M.A.
Medeiros,M.J.
Olivero,S.
Electrochemical Study of Nickel (salen) and Cobalt (salen) Derivative Complexes in the Presence of Unsaturated Halides
author_facet Duñach,E.
Esteves,A.P.
Leite,L.F.M.
Lemos,M.A.
Medeiros,M.J.
Olivero,S.
author_sort Duñach,E.
title Electrochemical Study of Nickel (salen) and Cobalt (salen) Derivative Complexes in the Presence of Unsaturated Halides
title_short Electrochemical Study of Nickel (salen) and Cobalt (salen) Derivative Complexes in the Presence of Unsaturated Halides
title_full Electrochemical Study of Nickel (salen) and Cobalt (salen) Derivative Complexes in the Presence of Unsaturated Halides
title_fullStr Electrochemical Study of Nickel (salen) and Cobalt (salen) Derivative Complexes in the Presence of Unsaturated Halides
title_full_unstemmed Electrochemical Study of Nickel (salen) and Cobalt (salen) Derivative Complexes in the Presence of Unsaturated Halides
title_sort electrochemical study of nickel (salen) and cobalt (salen) derivative complexes in the presence of unsaturated halides
description The electrochemical intramolecular cyclisation of allyl 2-bromophenyl ethers in N,N'-dimethylformamide at constant current in a diaphragmless cell has been developed using Ni(II) and Co(II) complexes as electron-transfer mediators. Cyclic compounds are obtained in good yields under appropriate experimental conditions.
publisher Sociedade Portuguesa de Electroquímica
publishDate 2003
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042003000200007
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