PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE

PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE

A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, ¹H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms.

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Main Authors: ALHADI,ABEER A, SHAKER,SHAYMA A, SULEIMAN G,NURA, YEHYE,WAGEE A, MOHD ALI,HAPIPAH
Format: Digital revista
Language:English
Published: Sociedad Chilena de Química 2012
Online Access:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300018
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spelling oai:scielo:S0717-970720120003000182019-02-19PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONEALHADI,ABEER ASHAKER,SHAYMA ASULEIMAN G,NURAYEHYE,WAGEE AMOHD ALI,HAPIPAH Schiff base derivatives Cd(II) complexes hydrazone derivatives complexes spectroscopic characterization A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, ¹H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.57 n.3 20122012-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300018en10.4067/S0717-97072012000300018
institution SCIELO
collection OJS
country Chile
countrycode CL
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access En linea
databasecode rev-scielo-cl
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region America del Sur
libraryname SciELO
language English
format Digital
author ALHADI,ABEER A
SHAKER,SHAYMA A
SULEIMAN G,NURA
YEHYE,WAGEE A
MOHD ALI,HAPIPAH
spellingShingle ALHADI,ABEER A
SHAKER,SHAYMA A
SULEIMAN G,NURA
YEHYE,WAGEE A
MOHD ALI,HAPIPAH
PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
author_facet ALHADI,ABEER A
SHAKER,SHAYMA A
SULEIMAN G,NURA
YEHYE,WAGEE A
MOHD ALI,HAPIPAH
author_sort ALHADI,ABEER A
title PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_short PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_full PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_fullStr PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_full_unstemmed PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
title_sort preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone
description A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, ¹H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms.
publisher Sociedad Chilena de Química
publishDate 2012
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000300018
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AT shakershaymaa preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
AT suleimangnura preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
AT yehyewageea preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
AT mohdalihapipah preparationspectroscopiccharacterizationofanewcdiicomplexcontainingtridentatennoschiffbasederivedandxraycrystallographicstructuralstudyof345trihydroxybenzoicacid1pyridylethylidenehydrazone
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