ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE

ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE

The copolymerization of carbazole(C) and poly3-ethyl-3-({[6-(3-thienyl)hexyl]oxy}-methyl)oxetane(PTO) was successfully achieved electrochemically in CH2Cl2 containing 25% boron trifluoride diethyl etherate BFEE(by volume) as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum or an optically transparent ITO electrode. As-formed copolymer own the advantages of PTO, such as good electrochemical behaviors, excellent ambient stability. The structure of the copolymer were investigated by UV-vis, fluorescence spectra and thermal analysis, respectively. The fluorescence spectra indicate that PPTOC films are yellow-light emitters. Thermal analysis studies confirmed PPTOC has a good thermal stability.

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Main Authors: GAO,CHUANG, PEI,MEISHAN, PAN,QIWEI
Format: Digital revista
Language:English
Published: Sociedad Chilena de Química 2012
Online Access:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000200019
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spelling oai:scielo:S0717-970720120002000192014-03-10ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLEGAO,CHUANGPEI,MEISHANPAN,QIWEI Polythiophene Electrochemical polymerization carbazole Copolymerization Boron trifluoride diethyl etherate The copolymerization of carbazole(C) and poly3-ethyl-3-({[6-(3-thienyl)hexyl]oxy}-methyl)oxetane(PTO) was successfully achieved electrochemically in CH2Cl2 containing 25% boron trifluoride diethyl etherate BFEE(by volume) as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum or an optically transparent ITO electrode. As-formed copolymer own the advantages of PTO, such as good electrochemical behaviors, excellent ambient stability. The structure of the copolymer were investigated by UV-vis, fluorescence spectra and thermal analysis, respectively. The fluorescence spectra indicate that PPTOC films are yellow-light emitters. Thermal analysis studies confirmed PPTOC has a good thermal stability.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.57 n.2 20122012-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000200019en10.4067/S0717-97072012000200019
institution SCIELO
collection OJS
country Chile
countrycode CL
component Revista
access En linea
databasecode rev-scielo-cl
tag revista
region America del Sur
libraryname SciELO
language English
format Digital
author GAO,CHUANG
PEI,MEISHAN
PAN,QIWEI
spellingShingle GAO,CHUANG
PEI,MEISHAN
PAN,QIWEI
ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
author_facet GAO,CHUANG
PEI,MEISHAN
PAN,QIWEI
author_sort GAO,CHUANG
title ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_short ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_full ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_fullStr ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_full_unstemmed ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
title_sort electrochemical copolymerization of cross-linkable polythiophene and carbazole
description The copolymerization of carbazole(C) and poly3-ethyl-3-({[6-(3-thienyl)hexyl]oxy}-methyl)oxetane(PTO) was successfully achieved electrochemically in CH2Cl2 containing 25% boron trifluoride diethyl etherate BFEE(by volume) as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum or an optically transparent ITO electrode. As-formed copolymer own the advantages of PTO, such as good electrochemical behaviors, excellent ambient stability. The structure of the copolymer were investigated by UV-vis, fluorescence spectra and thermal analysis, respectively. The fluorescence spectra indicate that PPTOC films are yellow-light emitters. Thermal analysis studies confirmed PPTOC has a good thermal stability.
publisher Sociedad Chilena de Química
publishDate 2012
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000200019
work_keys_str_mv AT gaochuang electrochemicalcopolymerizationofcrosslinkablepolythiopheneandcarbazole
AT peimeishan electrochemicalcopolymerizationofcrosslinkablepolythiopheneandcarbazole
AT panqiwei electrochemicalcopolymerizationofcrosslinkablepolythiopheneandcarbazole
_version_ 1755993476741201920

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