TRANSITION METAL BIS(2-BROMOPHENYL)DISULFIDE COMPLEXES
The interactions of the new ligand bis(2-bromophenyl)disulfide (BrPh)2S2 = L with transition metal ions are described. Octahedral complexes [ML2C1(2)(H(2)0)] (M = Mn(II), Fe(II), [Co(II) or Ni(II)) and CrL2Cl2(H(2)0)2]Cl were obtained and characterized by physicochemical and spectroscopic methods which suggest that the bis(2-bromophenyl)disulfide behaves as a monodentate ligand.
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| Main Authors: | , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedad Chilena de Química
2008
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| Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400012 |
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| Summary: | The interactions of the new ligand bis(2-bromophenyl)disulfide (BrPh)2S2 = L with transition metal ions are described. Octahedral complexes [ML2C1(2)(H(2)0)] (M = Mn(II), Fe(II), [Co(II) or Ni(II)) and CrL2Cl2(H(2)0)2]Cl were obtained and characterized by physicochemical and spectroscopic methods which suggest that the bis(2-bromophenyl)disulfide behaves as a monodentate ligand. |
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