SYNTHESIS AND CHARACTERIZATION OF 4-ARYLAMINOBIPHENYLGLYOXIMES AND THEIR COMPLEXES
4-Chloroacetylbiphenyl has been synthesized by Friedel-Crafts reaction between biphenyl and chloroacetyl chloride in the presence of AlCl3 catalyst. The nitrosation reaction of this compound gave 4-biphenylhydroxamyl chloride (HL). Subsequently, 4-biphenylchloroglyoxime (H2L) was prepared by the reaction of 4-biphenylhydroxamyl chloride and hydroxylamine hydrochloride. Then, six new substituted 4-biphenylaminoglyoximes (H2Lx) have been synthesized from 4-biphenylchloroglyoxime and the corresponding amines. A series of M(II)-dioxime complexes of the type [M(HLx)2] or [M(HLx)2(H2O)2] [M(II)=Co(II), Ni(II), Cu(II)] have been synthesized and characterized by FT-IR, ¹H NMR spectral studies, elemental analysis, AAS and magnetic susceptibility measurements
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedad Chilena de Química
2006
|
| Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000300012 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| id |
oai:scielo:S0717-97072006000300012 |
|---|---|
| record_format |
ojs |
| spelling |
oai:scielo:S0717-970720060003000122006-11-16SYNTHESIS AND CHARACTERIZATION OF 4-ARYLAMINOBIPHENYLGLYOXIMES AND THEIR COMPLEXESKARIPCIN,FATMAARABALI,FILIZ Dioximes Magnetic Properties Metal Complexes FT-IR 4-Chloroacetylbiphenyl has been synthesized by Friedel-Crafts reaction between biphenyl and chloroacetyl chloride in the presence of AlCl3 catalyst. The nitrosation reaction of this compound gave 4-biphenylhydroxamyl chloride (HL). Subsequently, 4-biphenylchloroglyoxime (H2L) was prepared by the reaction of 4-biphenylhydroxamyl chloride and hydroxylamine hydrochloride. Then, six new substituted 4-biphenylaminoglyoximes (H2Lx) have been synthesized from 4-biphenylchloroglyoxime and the corresponding amines. A series of M(II)-dioxime complexes of the type [M(HLx)2] or [M(HLx)2(H2O)2] [M(II)=Co(II), Ni(II), Cu(II)] have been synthesized and characterized by FT-IR, ¹H NMR spectral studies, elemental analysis, AAS and magnetic susceptibility measurementsinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.51 n.3 20062006-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000300012en10.4067/S0717-97072006000300012 |
| institution |
SCIELO |
| collection |
OJS |
| country |
Chile |
| countrycode |
CL |
| component |
Revista |
| access |
En linea |
| databasecode |
rev-scielo-cl |
| tag |
revista |
| region |
America del Sur |
| libraryname |
SciELO |
| language |
English |
| format |
Digital |
| author |
KARIPCIN,FATMA ARABALI,FILIZ |
| spellingShingle |
KARIPCIN,FATMA ARABALI,FILIZ SYNTHESIS AND CHARACTERIZATION OF 4-ARYLAMINOBIPHENYLGLYOXIMES AND THEIR COMPLEXES |
| author_facet |
KARIPCIN,FATMA ARABALI,FILIZ |
| author_sort |
KARIPCIN,FATMA |
| title |
SYNTHESIS AND CHARACTERIZATION OF 4-ARYLAMINOBIPHENYLGLYOXIMES AND THEIR COMPLEXES |
| title_short |
SYNTHESIS AND CHARACTERIZATION OF 4-ARYLAMINOBIPHENYLGLYOXIMES AND THEIR COMPLEXES |
| title_full |
SYNTHESIS AND CHARACTERIZATION OF 4-ARYLAMINOBIPHENYLGLYOXIMES AND THEIR COMPLEXES |
| title_fullStr |
SYNTHESIS AND CHARACTERIZATION OF 4-ARYLAMINOBIPHENYLGLYOXIMES AND THEIR COMPLEXES |
| title_full_unstemmed |
SYNTHESIS AND CHARACTERIZATION OF 4-ARYLAMINOBIPHENYLGLYOXIMES AND THEIR COMPLEXES |
| title_sort |
synthesis and characterization of 4-arylaminobiphenylglyoximes and their complexes |
| description |
4-Chloroacetylbiphenyl has been synthesized by Friedel-Crafts reaction between biphenyl and chloroacetyl chloride in the presence of AlCl3 catalyst. The nitrosation reaction of this compound gave 4-biphenylhydroxamyl chloride (HL). Subsequently, 4-biphenylchloroglyoxime (H2L) was prepared by the reaction of 4-biphenylhydroxamyl chloride and hydroxylamine hydrochloride. Then, six new substituted 4-biphenylaminoglyoximes (H2Lx) have been synthesized from 4-biphenylchloroglyoxime and the corresponding amines. A series of M(II)-dioxime complexes of the type [M(HLx)2] or [M(HLx)2(H2O)2] [M(II)=Co(II), Ni(II), Cu(II)] have been synthesized and characterized by FT-IR, ¹H NMR spectral studies, elemental analysis, AAS and magnetic susceptibility measurements |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2006 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072006000300012 |
| work_keys_str_mv |
AT karipcinfatma synthesisandcharacterizationof4arylaminobiphenylglyoximesandtheircomplexes AT arabalifiliz synthesisandcharacterizationof4arylaminobiphenylglyoximesandtheircomplexes |
| _version_ |
1755993403135361024 |