Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
A library of chiral Schiff base ligands was synthesized from aromatic aldehydes and chiral amino alcohols. These ligands were then screened as catalysts in the asymmetric ring opening of meso-cyclohexene epoxide with phenyllithium to give (1S,2R)-phenylcyclohexanol in 9-67% ee.
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| Main Authors: | , , , , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedad Química de México A.C.
2004
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| Online Access: | http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S0583-76932004000100011 |
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