Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands

Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands

A library of chiral Schiff base ligands was synthesized from aromatic aldehydes and chiral amino alcohols. These ligands were then screened as catalysts in the asymmetric ring opening of meso-cyclohexene epoxide with phenyllithium to give (1S,2R)-phenylcyclohexanol in 9-67% ee.

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Bibliographic Details
Main Authors: Cortez,Norma Aidé, Flores-López,Lucía Z., Parra-Hake,Miguel, Aguirre,Gerardo, Hellberg,Lars H., Somanathan,Ratnasamy
Format: Digital revista
Language:English
Published: Sociedad Química de México A.C. 2004
Online Access:http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S0583-76932004000100011
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spelling oai:scielo:S0583-769320040001000112017-02-19Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base LigandsCortez,Norma AidéFlores-López,Lucía Z.Parra-Hake,MiguelAguirre,GerardoHellberg,Lars H.Somanathan,Ratnasamy Chiral Schiff base meso-cyclohexene epoxide phenyllithium ring opening A library of chiral Schiff base ligands was synthesized from aromatic aldehydes and chiral amino alcohols. These ligands were then screened as catalysts in the asymmetric ring opening of meso-cyclohexene epoxide with phenyllithium to give (1S,2R)-phenylcyclohexanol in 9-67% ee.info:eu-repo/semantics/openAccessSociedad Química de México A.C.Revista de la Sociedad Química de México v.48 n.1 20042004-03-01info:eu-repo/semantics/articletext/htmlhttp://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S0583-76932004000100011en
institution SCIELO
collection OJS
country México
countrycode MX
component Revista
access En linea
databasecode rev-scielo-mx
tag revista
region America del Norte
libraryname SciELO
language English
format Digital
author Cortez,Norma Aidé
Flores-López,Lucía Z.
Parra-Hake,Miguel
Aguirre,Gerardo
Hellberg,Lars H.
Somanathan,Ratnasamy
spellingShingle Cortez,Norma Aidé
Flores-López,Lucía Z.
Parra-Hake,Miguel
Aguirre,Gerardo
Hellberg,Lars H.
Somanathan,Ratnasamy
Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
author_facet Cortez,Norma Aidé
Flores-López,Lucía Z.
Parra-Hake,Miguel
Aguirre,Gerardo
Hellberg,Lars H.
Somanathan,Ratnasamy
author_sort Cortez,Norma Aidé
title Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
title_short Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
title_full Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
title_fullStr Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
title_full_unstemmed Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
title_sort enantioselective ring opening of meso-cyclohexene epoxide with phenyllithium catalyzed by chiral schiff base ligands
description A library of chiral Schiff base ligands was synthesized from aromatic aldehydes and chiral amino alcohols. These ligands were then screened as catalysts in the asymmetric ring opening of meso-cyclohexene epoxide with phenyllithium to give (1S,2R)-phenylcyclohexanol in 9-67% ee.
publisher Sociedad Química de México A.C.
publishDate 2004
url http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S0583-76932004000100011
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AT floreslopezluciaz enantioselectiveringopeningofmesocyclohexeneepoxidewithphenyllithiumcatalyzedbychiralschiffbaseligands
AT parrahakemiguel enantioselectiveringopeningofmesocyclohexeneepoxidewithphenyllithiumcatalyzedbychiralschiffbaseligands
AT aguirregerardo enantioselectiveringopeningofmesocyclohexeneepoxidewithphenyllithiumcatalyzedbychiralschiffbaseligands
AT hellberglarsh enantioselectiveringopeningofmesocyclohexeneepoxidewithphenyllithiumcatalyzedbychiralschiffbaseligands
AT somanathanratnasamy enantioselectiveringopeningofmesocyclohexeneepoxidewithphenyllithiumcatalyzedbychiralschiffbaseligands
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