A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyne
An efficient, convenient and inexpensive CuI-catalyzed method for the synthesis of 1,2-dichlorovinylphosphine oxides from substituted phosphites, diphenylphosphine oxide and 1,2-dichloroethyne has been developed in moderate-good yields, and the reactions provided mainly regioselective anti addition products.
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The South African Chemical Institute
2012
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| Online Access: | http://www.scielo.org.za/scielo.php?script=sci_arttext&pid=S0379-43502012000100043 |
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oai:scielo:S0379-435020120001000432015-07-16A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyneZhang,Xiang-ZhuMa,Jing-YaWu,Ming-shu Copper-catalyzed addition reaction 1,2-dichlorovinylphosphine oxides An efficient, convenient and inexpensive CuI-catalyzed method for the synthesis of 1,2-dichlorovinylphosphine oxides from substituted phosphites, diphenylphosphine oxide and 1,2-dichloroethyne has been developed in moderate-good yields, and the reactions provided mainly regioselective anti addition products.The South African Chemical InstituteSouth African Journal of Chemistry v.65 20122012-01-01journal articletext/htmlhttp://www.scielo.org.za/scielo.php?script=sci_arttext&pid=S0379-43502012000100043en |
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| author |
Zhang,Xiang-Zhu Ma,Jing-Ya Wu,Ming-shu |
| spellingShingle |
Zhang,Xiang-Zhu Ma,Jing-Ya Wu,Ming-shu A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyne |
| author_facet |
Zhang,Xiang-Zhu Ma,Jing-Ya Wu,Ming-shu |
| author_sort |
Zhang,Xiang-Zhu |
| title |
A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyne |
| title_short |
A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyne |
| title_full |
A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyne |
| title_fullStr |
A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyne |
| title_full_unstemmed |
A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyne |
| title_sort |
convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of h-phosphine oxides to 1,2-dichloroethyne |
| description |
An efficient, convenient and inexpensive CuI-catalyzed method for the synthesis of 1,2-dichlorovinylphosphine oxides from substituted phosphites, diphenylphosphine oxide and 1,2-dichloroethyne has been developed in moderate-good yields, and the reactions provided mainly regioselective anti addition products. |
| publisher |
The South African Chemical Institute |
| publishDate |
2012 |
| url |
http://www.scielo.org.za/scielo.php?script=sci_arttext&pid=S0379-43502012000100043 |
| work_keys_str_mv |
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| _version_ |
1756006630033457152 |