The evaluation of novel camphor-derived ligands as catalysts in the asymmetric Henry reaction
The evaluation of a series of camphor-derived ligands as catalysts in the asymmetric Henry reaction is reported. The synthesis of two novel derivatives is detailed and these molecules are also screened as catalysts in this reaction. The single crystal X-ray structure of one of the novel compounds is reported. The reaction is catalyzed with moderate to excellent yields and moderate enantioselectivity.
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The South African Chemical Institute
2009
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oai:scielo:S0379-435020090001000212015-07-16The evaluation of novel camphor-derived ligands as catalysts in the asymmetric Henry reactionBoyle,Grant A.Govender,ThavendranKruger,Hendrik G.Maguire,Glenn E.M. Camphor asymmetric catalysis Henry reaction chiral ligands The evaluation of a series of camphor-derived ligands as catalysts in the asymmetric Henry reaction is reported. The synthesis of two novel derivatives is detailed and these molecules are also screened as catalysts in this reaction. The single crystal X-ray structure of one of the novel compounds is reported. The reaction is catalyzed with moderate to excellent yields and moderate enantioselectivity.The South African Chemical InstituteSouth African Journal of Chemistry v.62 20092009-01-01journal articletext/htmlhttp://www.scielo.org.za/scielo.php?script=sci_arttext&pid=S0379-43502009000100021en |
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Boyle,Grant A. Govender,Thavendran Kruger,Hendrik G. Maguire,Glenn E.M. |
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Boyle,Grant A. Govender,Thavendran Kruger,Hendrik G. Maguire,Glenn E.M. The evaluation of novel camphor-derived ligands as catalysts in the asymmetric Henry reaction |
author_facet |
Boyle,Grant A. Govender,Thavendran Kruger,Hendrik G. Maguire,Glenn E.M. |
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Boyle,Grant A. |
title |
The evaluation of novel camphor-derived ligands as catalysts in the asymmetric Henry reaction |
title_short |
The evaluation of novel camphor-derived ligands as catalysts in the asymmetric Henry reaction |
title_full |
The evaluation of novel camphor-derived ligands as catalysts in the asymmetric Henry reaction |
title_fullStr |
The evaluation of novel camphor-derived ligands as catalysts in the asymmetric Henry reaction |
title_full_unstemmed |
The evaluation of novel camphor-derived ligands as catalysts in the asymmetric Henry reaction |
title_sort |
evaluation of novel camphor-derived ligands as catalysts in the asymmetric henry reaction |
description |
The evaluation of a series of camphor-derived ligands as catalysts in the asymmetric Henry reaction is reported. The synthesis of two novel derivatives is detailed and these molecules are also screened as catalysts in this reaction. The single crystal X-ray structure of one of the novel compounds is reported. The reaction is catalyzed with moderate to excellent yields and moderate enantioselectivity. |
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The South African Chemical Institute |
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2009 |
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http://www.scielo.org.za/scielo.php?script=sci_arttext&pid=S0379-43502009000100021 |
work_keys_str_mv |
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