Polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterization

Abstract This work provides a convenient strategy for preparation of conducting polycaprolactone (PCL)/polyaniline (PAni) nanofibers, useful for development of optoelectronic sensors and devices. PCL/PAni nanofibers were obtained by electrospinning technique and characterized by SEM, FTIR, thermal analysis, and DC electrical conductivity. The influence of the experimental conditions in the electrospinning process, such as the applied voltage, on the nanofiber morphology was discussed in detail. Incorporation of PAni into PCL nanofibers significantly increased the electrical conductivity from a non-detectable level for the neat PCL to 0.032 ± 0.022 S/cm for the nanofibers containing 7.5 wt.% PAni. Therefore, electrospun PCL/PAni nanofiber mats presented optical and electrical properties, that awaken the possibility of applications for these materials as acid-base sensors and electrochromic devices.

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Main Authors: Cantalice,Juliana Donato de Almeida, Mazzini Júnior,Edu Grieco, Freitas,Johnnatan Duarte de, Silva,Rosanny Christinny da, Faez,Roselena, Costa,Ligia Maria Manzine, Ribeiro,Adriana Santos
Format: Digital revista
Language:English
Published: Associação Brasileira de Polímeros 2021
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100404
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spelling oai:scielo:S0104-142820210001004042021-05-07Polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterizationCantalice,Juliana Donato de AlmeidaMazzini Júnior,Edu GriecoFreitas,Johnnatan Duarte deSilva,Rosanny Christinny daFaez,RoselenaCosta,Ligia Maria ManzineRibeiro,Adriana Santos electrospinning nanofibers polyaniline polycaprolactone Abstract This work provides a convenient strategy for preparation of conducting polycaprolactone (PCL)/polyaniline (PAni) nanofibers, useful for development of optoelectronic sensors and devices. PCL/PAni nanofibers were obtained by electrospinning technique and characterized by SEM, FTIR, thermal analysis, and DC electrical conductivity. The influence of the experimental conditions in the electrospinning process, such as the applied voltage, on the nanofiber morphology was discussed in detail. Incorporation of PAni into PCL nanofibers significantly increased the electrical conductivity from a non-detectable level for the neat PCL to 0.032 ± 0.022 S/cm for the nanofibers containing 7.5 wt.% PAni. Therefore, electrospun PCL/PAni nanofiber mats presented optical and electrical properties, that awaken the possibility of applications for these materials as acid-base sensors and electrochromic devices.info:eu-repo/semantics/openAccessAssociação Brasileira de PolímerosPolímeros v.31 n.1 20212021-01-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100404en10.1590/0104-1428.09320
institution SCIELO
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country Brasil
countrycode BR
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access En linea
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region America del Sur
libraryname SciELO
language English
format Digital
author Cantalice,Juliana Donato de Almeida
Mazzini Júnior,Edu Grieco
Freitas,Johnnatan Duarte de
Silva,Rosanny Christinny da
Faez,Roselena
Costa,Ligia Maria Manzine
Ribeiro,Adriana Santos
spellingShingle Cantalice,Juliana Donato de Almeida
Mazzini Júnior,Edu Grieco
Freitas,Johnnatan Duarte de
Silva,Rosanny Christinny da
Faez,Roselena
Costa,Ligia Maria Manzine
Ribeiro,Adriana Santos
Polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterization
author_facet Cantalice,Juliana Donato de Almeida
Mazzini Júnior,Edu Grieco
Freitas,Johnnatan Duarte de
Silva,Rosanny Christinny da
Faez,Roselena
Costa,Ligia Maria Manzine
Ribeiro,Adriana Santos
author_sort Cantalice,Juliana Donato de Almeida
title Polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterization
title_short Polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterization
title_full Polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterization
title_fullStr Polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterization
title_full_unstemmed Polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterization
title_sort polyaniline-based electrospun polycaprolactone nanofibers: preparation and characterization
description Abstract This work provides a convenient strategy for preparation of conducting polycaprolactone (PCL)/polyaniline (PAni) nanofibers, useful for development of optoelectronic sensors and devices. PCL/PAni nanofibers were obtained by electrospinning technique and characterized by SEM, FTIR, thermal analysis, and DC electrical conductivity. The influence of the experimental conditions in the electrospinning process, such as the applied voltage, on the nanofiber morphology was discussed in detail. Incorporation of PAni into PCL nanofibers significantly increased the electrical conductivity from a non-detectable level for the neat PCL to 0.032 ± 0.022 S/cm for the nanofibers containing 7.5 wt.% PAni. Therefore, electrospun PCL/PAni nanofiber mats presented optical and electrical properties, that awaken the possibility of applications for these materials as acid-base sensors and electrochromic devices.
publisher Associação Brasileira de Polímeros
publishDate 2021
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100404
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