Gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite films

Abstract Polycaprolactone (PCL) to which has been added zinc oxide nanoparticles (ZnO NPs) produces nanocomposites (PCL/ZnO NCs). These nanocomposites can be used in biomedical applications and in the food packaging sector. However, for these materials to be used in these applications, they need to be sterilized. For this, gamma irradiation is the most common method. Thus it is important to evaluate the effects of gamma irradiation on the properties of PCL and PCL/ZnO that have been exposed to gamma irradiation. PCL/ZnO NCs films were obtained by solvent casting and exposed to gamma irradiation at 25 kGy and evaluated by Fourier transform infrared spectra (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) scanning electron microscopy (SEM) and mechanical properties. Mechanical properties and crystallinity showed marginal variations for the irradiated samples. The results obtained demonstrate that gamma irradiation at 25 kGy, did not cause profound changes in nanocomposite properties.

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Main Authors: Paula,Marcos, Diego,Ivo, Dionisio,Ronaldo, Vinhas,Glória, Alves,Severino
Format: Digital revista
Language:English
Published: Associação Brasileira de Polímeros 2019
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000100412
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spelling oai:scielo:S0104-142820190001004122019-03-18Gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite filmsPaula,MarcosDiego,IvoDionisio,RonaldoVinhas,GlóriaAlves,Severino polycaprolactone gamma irradiation nanocomposites materials properties Abstract Polycaprolactone (PCL) to which has been added zinc oxide nanoparticles (ZnO NPs) produces nanocomposites (PCL/ZnO NCs). These nanocomposites can be used in biomedical applications and in the food packaging sector. However, for these materials to be used in these applications, they need to be sterilized. For this, gamma irradiation is the most common method. Thus it is important to evaluate the effects of gamma irradiation on the properties of PCL and PCL/ZnO that have been exposed to gamma irradiation. PCL/ZnO NCs films were obtained by solvent casting and exposed to gamma irradiation at 25 kGy and evaluated by Fourier transform infrared spectra (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) scanning electron microscopy (SEM) and mechanical properties. Mechanical properties and crystallinity showed marginal variations for the irradiated samples. The results obtained demonstrate that gamma irradiation at 25 kGy, did not cause profound changes in nanocomposite properties.info:eu-repo/semantics/openAccessAssociação Brasileira de PolímerosPolímeros v.29 n.1 20192019-01-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000100412en10.1590/0104-1428.04018
institution SCIELO
collection OJS
country Brasil
countrycode BR
component Revista
access En linea
databasecode rev-scielo-br
tag revista
region America del Sur
libraryname SciELO
language English
format Digital
author Paula,Marcos
Diego,Ivo
Dionisio,Ronaldo
Vinhas,Glória
Alves,Severino
spellingShingle Paula,Marcos
Diego,Ivo
Dionisio,Ronaldo
Vinhas,Glória
Alves,Severino
Gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite films
author_facet Paula,Marcos
Diego,Ivo
Dionisio,Ronaldo
Vinhas,Glória
Alves,Severino
author_sort Paula,Marcos
title Gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite films
title_short Gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite films
title_full Gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite films
title_fullStr Gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite films
title_full_unstemmed Gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite films
title_sort gamma irradiation effects on polycaprolactone/zinc oxide nanocomposite films
description Abstract Polycaprolactone (PCL) to which has been added zinc oxide nanoparticles (ZnO NPs) produces nanocomposites (PCL/ZnO NCs). These nanocomposites can be used in biomedical applications and in the food packaging sector. However, for these materials to be used in these applications, they need to be sterilized. For this, gamma irradiation is the most common method. Thus it is important to evaluate the effects of gamma irradiation on the properties of PCL and PCL/ZnO that have been exposed to gamma irradiation. PCL/ZnO NCs films were obtained by solvent casting and exposed to gamma irradiation at 25 kGy and evaluated by Fourier transform infrared spectra (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) scanning electron microscopy (SEM) and mechanical properties. Mechanical properties and crystallinity showed marginal variations for the irradiated samples. The results obtained demonstrate that gamma irradiation at 25 kGy, did not cause profound changes in nanocomposite properties.
publisher Associação Brasileira de Polímeros
publishDate 2019
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000100412
work_keys_str_mv AT paulamarcos gammairradiationeffectsonpolycaprolactonezincoxidenanocompositefilms
AT diegoivo gammairradiationeffectsonpolycaprolactonezincoxidenanocompositefilms
AT dionisioronaldo gammairradiationeffectsonpolycaprolactonezincoxidenanocompositefilms
AT vinhasgloria gammairradiationeffectsonpolycaprolactonezincoxidenanocompositefilms
AT alvesseverino gammairradiationeffectsonpolycaprolactonezincoxidenanocompositefilms
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