Antioxidant Activity and Metabolomic Analysis of Cagaitas (Eugenia dysenterica) using Paper Spray Mass Spectrometry

Cagaita is a fruit from Brazilian cerrado, belongs to Myrtaceae family, and has important economic value. This work aimed to determine the total antioxidant capacity (extractable and non-extractable fractions) by different methods and to evaluate the use of paper spray mass spectrometry to obtain fingerprints of cagaita from different regions with the aid of principal components analysis. Cagaitas had higher antioxidant activity than those found in other fruits mentioned in literature, and the non-extractable fraction was 18.90 to 21.05% of the antioxidant capacity. The analysis of paper spray mass spectrometry in positive and negative ionization modes identified several substances, including organic acids, sugars, amino acids and several other classes of phenolic compounds. Analysis of the main components of cagaita samples permitted discrimination of the major constituents such as sugars and different kinds of phenolic compounds. Thus, this study demonstrated that paper spray mass spectrometry is a simple and ultrafast method with minimum sample preparation that allows the analysis of the chemical profile of cagaita.

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Main Authors: Silva,Mauro R., Freitas,Lucas G., Souza,Amauri G., Araújo,Raquel L. B., Lacerda,Inayara C. A., Pereira,Hebert V., Augusti,Rodinei, Melo,Júlio O. F.
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2019
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000501034
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spelling oai:scielo:S0103-505320190005010342019-04-02Antioxidant Activity and Metabolomic Analysis of Cagaitas (Eugenia dysenterica) using Paper Spray Mass SpectrometrySilva,Mauro R.Freitas,Lucas G.Souza,Amauri G.Araújo,Raquel L. B.Lacerda,Inayara C. A.Pereira,Hebert V.Augusti,RodineiMelo,Júlio O. F. paper spray principal components analysis ABTS FRAP DPPH Cagaita is a fruit from Brazilian cerrado, belongs to Myrtaceae family, and has important economic value. This work aimed to determine the total antioxidant capacity (extractable and non-extractable fractions) by different methods and to evaluate the use of paper spray mass spectrometry to obtain fingerprints of cagaita from different regions with the aid of principal components analysis. Cagaitas had higher antioxidant activity than those found in other fruits mentioned in literature, and the non-extractable fraction was 18.90 to 21.05% of the antioxidant capacity. The analysis of paper spray mass spectrometry in positive and negative ionization modes identified several substances, including organic acids, sugars, amino acids and several other classes of phenolic compounds. Analysis of the main components of cagaita samples permitted discrimination of the major constituents such as sugars and different kinds of phenolic compounds. Thus, this study demonstrated that paper spray mass spectrometry is a simple and ultrafast method with minimum sample preparation that allows the analysis of the chemical profile of cagaita.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society v.30 n.5 20192019-05-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000501034en10.21577/0103-5053.20190002
institution SCIELO
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country Brasil
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databasecode rev-scielo-br
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region America del Sur
libraryname SciELO
language English
format Digital
author Silva,Mauro R.
Freitas,Lucas G.
Souza,Amauri G.
Araújo,Raquel L. B.
Lacerda,Inayara C. A.
Pereira,Hebert V.
Augusti,Rodinei
Melo,Júlio O. F.
spellingShingle Silva,Mauro R.
Freitas,Lucas G.
Souza,Amauri G.
Araújo,Raquel L. B.
Lacerda,Inayara C. A.
Pereira,Hebert V.
Augusti,Rodinei
Melo,Júlio O. F.
Antioxidant Activity and Metabolomic Analysis of Cagaitas (Eugenia dysenterica) using Paper Spray Mass Spectrometry
author_facet Silva,Mauro R.
Freitas,Lucas G.
Souza,Amauri G.
Araújo,Raquel L. B.
Lacerda,Inayara C. A.
Pereira,Hebert V.
Augusti,Rodinei
Melo,Júlio O. F.
author_sort Silva,Mauro R.
title Antioxidant Activity and Metabolomic Analysis of Cagaitas (Eugenia dysenterica) using Paper Spray Mass Spectrometry
title_short Antioxidant Activity and Metabolomic Analysis of Cagaitas (Eugenia dysenterica) using Paper Spray Mass Spectrometry
title_full Antioxidant Activity and Metabolomic Analysis of Cagaitas (Eugenia dysenterica) using Paper Spray Mass Spectrometry
title_fullStr Antioxidant Activity and Metabolomic Analysis of Cagaitas (Eugenia dysenterica) using Paper Spray Mass Spectrometry
title_full_unstemmed Antioxidant Activity and Metabolomic Analysis of Cagaitas (Eugenia dysenterica) using Paper Spray Mass Spectrometry
title_sort antioxidant activity and metabolomic analysis of cagaitas (eugenia dysenterica) using paper spray mass spectrometry
description Cagaita is a fruit from Brazilian cerrado, belongs to Myrtaceae family, and has important economic value. This work aimed to determine the total antioxidant capacity (extractable and non-extractable fractions) by different methods and to evaluate the use of paper spray mass spectrometry to obtain fingerprints of cagaita from different regions with the aid of principal components analysis. Cagaitas had higher antioxidant activity than those found in other fruits mentioned in literature, and the non-extractable fraction was 18.90 to 21.05% of the antioxidant capacity. The analysis of paper spray mass spectrometry in positive and negative ionization modes identified several substances, including organic acids, sugars, amino acids and several other classes of phenolic compounds. Analysis of the main components of cagaita samples permitted discrimination of the major constituents such as sugars and different kinds of phenolic compounds. Thus, this study demonstrated that paper spray mass spectrometry is a simple and ultrafast method with minimum sample preparation that allows the analysis of the chemical profile of cagaita.
publisher Sociedade Brasileira de Química
publishDate 2019
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000501034
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