β-Enaminoesters as Novel Corrosion Inhibitors for Carbon Steel in Acidic Medium

In this work, two β-enaminoesters, EN1 and EN2, were synthesized, characterized and their anticorrosion effects on American Iron and Steel Institute (AISI) 1020 carbon steel in 0.5 mol L-1 HCl were investigated using gravimetric and electrochemical methods. The results revealed that both compounds inhibit corrosion. Good correlations were observed between results obtained for gravimetric and electrochemical methods. EN1 exhibited highest efficiency of 98% after 24 h of immersion in HCl solution. The adsorption of compounds on steel surface followed the modified Langmuir adsorption isotherm. Surface morphology of carbon steel was examined using scanning electron microscopy showing that the metal surface was protected by EN1 as inhibitor of corrosion.

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Main Authors: Carlos,Mariana F. L. P., Valbon,Arthur, Neves,Marcelo A., Santos,Margareth R. L., Echevarria,Aurea
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2018
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532018001202542
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spelling oai:scielo:S0103-505320180012025422018-11-26β-Enaminoesters as Novel Corrosion Inhibitors for Carbon Steel in Acidic MediumCarlos,Mariana F. L. P.Valbon,ArthurNeves,Marcelo A.Santos,Margareth R. L.Echevarria,Aurea corrosion β-enaminoesters EIS LRP mass loss In this work, two β-enaminoesters, EN1 and EN2, were synthesized, characterized and their anticorrosion effects on American Iron and Steel Institute (AISI) 1020 carbon steel in 0.5 mol L-1 HCl were investigated using gravimetric and electrochemical methods. The results revealed that both compounds inhibit corrosion. Good correlations were observed between results obtained for gravimetric and electrochemical methods. EN1 exhibited highest efficiency of 98% after 24 h of immersion in HCl solution. The adsorption of compounds on steel surface followed the modified Langmuir adsorption isotherm. Surface morphology of carbon steel was examined using scanning electron microscopy showing that the metal surface was protected by EN1 as inhibitor of corrosion.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society v.29 n.12 20182018-12-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532018001202542en10.21577/0103-5053.20180133
institution SCIELO
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country Brasil
countrycode BR
component Revista
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databasecode rev-scielo-br
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region America del Sur
libraryname SciELO
language English
format Digital
author Carlos,Mariana F. L. P.
Valbon,Arthur
Neves,Marcelo A.
Santos,Margareth R. L.
Echevarria,Aurea
spellingShingle Carlos,Mariana F. L. P.
Valbon,Arthur
Neves,Marcelo A.
Santos,Margareth R. L.
Echevarria,Aurea
β-Enaminoesters as Novel Corrosion Inhibitors for Carbon Steel in Acidic Medium
author_facet Carlos,Mariana F. L. P.
Valbon,Arthur
Neves,Marcelo A.
Santos,Margareth R. L.
Echevarria,Aurea
author_sort Carlos,Mariana F. L. P.
title β-Enaminoesters as Novel Corrosion Inhibitors for Carbon Steel in Acidic Medium
title_short β-Enaminoesters as Novel Corrosion Inhibitors for Carbon Steel in Acidic Medium
title_full β-Enaminoesters as Novel Corrosion Inhibitors for Carbon Steel in Acidic Medium
title_fullStr β-Enaminoesters as Novel Corrosion Inhibitors for Carbon Steel in Acidic Medium
title_full_unstemmed β-Enaminoesters as Novel Corrosion Inhibitors for Carbon Steel in Acidic Medium
title_sort β-enaminoesters as novel corrosion inhibitors for carbon steel in acidic medium
description In this work, two β-enaminoesters, EN1 and EN2, were synthesized, characterized and their anticorrosion effects on American Iron and Steel Institute (AISI) 1020 carbon steel in 0.5 mol L-1 HCl were investigated using gravimetric and electrochemical methods. The results revealed that both compounds inhibit corrosion. Good correlations were observed between results obtained for gravimetric and electrochemical methods. EN1 exhibited highest efficiency of 98% after 24 h of immersion in HCl solution. The adsorption of compounds on steel surface followed the modified Langmuir adsorption isotherm. Surface morphology of carbon steel was examined using scanning electron microscopy showing that the metal surface was protected by EN1 as inhibitor of corrosion.
publisher Sociedade Brasileira de Química
publishDate 2018
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532018001202542
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