Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils

Photoacoustic spectroscopy was used to obtain optical properties of edible soybean, canola and olive oils as well to evaluate the oil modifications induced by thermal treatment. The normalized photoacoustic signal intensity and its phase were independently measured as a function of wavelength of the radiation source. The oil samples were heated up to the smoke point and then for additional 30 min in order to degrade them. After, the oil samples were cooled down and photoacoustic measurements were conducted in order to obtain the absorption spectra of samples at both degraded and non-degraded conditions. Comparisons between the two conditions indicate that the degraded oil samples exhibited widening of the absorption bands in ultraviolet region of the spectra, relative to the respective non-degraded sample. Also, the peaks of those absorption bands presented a red shift.

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Main Authors: Albuquerque,José Eduardo de, Santiago,Bruno C. L., Campos,Júlio César C., Reis,Alexandre M., Silva,Charles L. da, Martins,João Paulo, Coimbra,Jane S. R.
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2013
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300002
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spelling oai:scielo:S0103-505320130003000022013-05-24Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oilsAlbuquerque,José Eduardo deSantiago,Bruno C. L.Campos,Júlio César C.Reis,Alexandre M.Silva,Charles L. daMartins,João PauloCoimbra,Jane S. R. thermal degradation fatty acid food process physicochemical properties vegetable oil Photoacoustic spectroscopy was used to obtain optical properties of edible soybean, canola and olive oils as well to evaluate the oil modifications induced by thermal treatment. The normalized photoacoustic signal intensity and its phase were independently measured as a function of wavelength of the radiation source. The oil samples were heated up to the smoke point and then for additional 30 min in order to degrade them. After, the oil samples were cooled down and photoacoustic measurements were conducted in order to obtain the absorption spectra of samples at both degraded and non-degraded conditions. Comparisons between the two conditions indicate that the degraded oil samples exhibited widening of the absorption bands in ultraviolet region of the spectra, relative to the respective non-degraded sample. Also, the peaks of those absorption bands presented a red shift.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society v.24 n.3 20132013-03-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300002en10.5935/0103-5053.20130047
institution SCIELO
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country Brasil
countrycode BR
component Revista
access En linea
databasecode rev-scielo-br
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region America del Sur
libraryname SciELO
language English
format Digital
author Albuquerque,José Eduardo de
Santiago,Bruno C. L.
Campos,Júlio César C.
Reis,Alexandre M.
Silva,Charles L. da
Martins,João Paulo
Coimbra,Jane S. R.
spellingShingle Albuquerque,José Eduardo de
Santiago,Bruno C. L.
Campos,Júlio César C.
Reis,Alexandre M.
Silva,Charles L. da
Martins,João Paulo
Coimbra,Jane S. R.
Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils
author_facet Albuquerque,José Eduardo de
Santiago,Bruno C. L.
Campos,Júlio César C.
Reis,Alexandre M.
Silva,Charles L. da
Martins,João Paulo
Coimbra,Jane S. R.
author_sort Albuquerque,José Eduardo de
title Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils
title_short Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils
title_full Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils
title_fullStr Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils
title_full_unstemmed Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils
title_sort photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils
description Photoacoustic spectroscopy was used to obtain optical properties of edible soybean, canola and olive oils as well to evaluate the oil modifications induced by thermal treatment. The normalized photoacoustic signal intensity and its phase were independently measured as a function of wavelength of the radiation source. The oil samples were heated up to the smoke point and then for additional 30 min in order to degrade them. After, the oil samples were cooled down and photoacoustic measurements were conducted in order to obtain the absorption spectra of samples at both degraded and non-degraded conditions. Comparisons between the two conditions indicate that the degraded oil samples exhibited widening of the absorption bands in ultraviolet region of the spectra, relative to the respective non-degraded sample. Also, the peaks of those absorption bands presented a red shift.
publisher Sociedade Brasileira de Química
publishDate 2013
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300002
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