Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils
Photoacoustic spectroscopy was used to obtain optical properties of edible soybean, canola and olive oils as well to evaluate the oil modifications induced by thermal treatment. The normalized photoacoustic signal intensity and its phase were independently measured as a function of wavelength of the radiation source. The oil samples were heated up to the smoke point and then for additional 30 min in order to degrade them. After, the oil samples were cooled down and photoacoustic measurements were conducted in order to obtain the absorption spectra of samples at both degraded and non-degraded conditions. Comparisons between the two conditions indicate that the degraded oil samples exhibited widening of the absorption bands in ultraviolet region of the spectra, relative to the respective non-degraded sample. Also, the peaks of those absorption bands presented a red shift.
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Sociedade Brasileira de Química
2013
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oai:scielo:S0103-505320130003000022013-05-24Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oilsAlbuquerque,José Eduardo deSantiago,Bruno C. L.Campos,Júlio César C.Reis,Alexandre M.Silva,Charles L. daMartins,João PauloCoimbra,Jane S. R. thermal degradation fatty acid food process physicochemical properties vegetable oil Photoacoustic spectroscopy was used to obtain optical properties of edible soybean, canola and olive oils as well to evaluate the oil modifications induced by thermal treatment. The normalized photoacoustic signal intensity and its phase were independently measured as a function of wavelength of the radiation source. The oil samples were heated up to the smoke point and then for additional 30 min in order to degrade them. After, the oil samples were cooled down and photoacoustic measurements were conducted in order to obtain the absorption spectra of samples at both degraded and non-degraded conditions. Comparisons between the two conditions indicate that the degraded oil samples exhibited widening of the absorption bands in ultraviolet region of the spectra, relative to the respective non-degraded sample. Also, the peaks of those absorption bands presented a red shift.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society v.24 n.3 20132013-03-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300002en10.5935/0103-5053.20130047 |
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Albuquerque,José Eduardo de Santiago,Bruno C. L. Campos,Júlio César C. Reis,Alexandre M. Silva,Charles L. da Martins,João Paulo Coimbra,Jane S. R. |
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Albuquerque,José Eduardo de Santiago,Bruno C. L. Campos,Júlio César C. Reis,Alexandre M. Silva,Charles L. da Martins,João Paulo Coimbra,Jane S. R. Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils |
author_facet |
Albuquerque,José Eduardo de Santiago,Bruno C. L. Campos,Júlio César C. Reis,Alexandre M. Silva,Charles L. da Martins,João Paulo Coimbra,Jane S. R. |
author_sort |
Albuquerque,José Eduardo de |
title |
Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils |
title_short |
Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils |
title_full |
Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils |
title_fullStr |
Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils |
title_full_unstemmed |
Photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils |
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photoacoustic spectroscopy as an approach to assess chemical modifications in edible oils |
description |
Photoacoustic spectroscopy was used to obtain optical properties of edible soybean, canola and olive oils as well to evaluate the oil modifications induced by thermal treatment. The normalized photoacoustic signal intensity and its phase were independently measured as a function of wavelength of the radiation source. The oil samples were heated up to the smoke point and then for additional 30 min in order to degrade them. After, the oil samples were cooled down and photoacoustic measurements were conducted in order to obtain the absorption spectra of samples at both degraded and non-degraded conditions. Comparisons between the two conditions indicate that the degraded oil samples exhibited widening of the absorption bands in ultraviolet region of the spectra, relative to the respective non-degraded sample. Also, the peaks of those absorption bands presented a red shift. |
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Sociedade Brasileira de Química |
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2013 |
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http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300002 |
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