Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil

The distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain.

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Main Authors: Santos,Izaias S., Garcia,Carlos A. B., Passos,Elisangela A., Alves,Jose P. H.
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2013
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011
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spelling oai:scielo:S0103-505320130002000112013-05-20Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast BrazilSantos,Izaias S.Garcia,Carlos A. B.Passos,Elisangela A.Alves,Jose P. H. reservoir sediment trace metals PCA bioavailability toxicity The distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society v.24 n.2 20132013-02-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011en10.5935/0103-5053.20130032
institution SCIELO
collection OJS
country Brasil
countrycode BR
component Revista
access En linea
databasecode rev-scielo-br
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region America del Sur
libraryname SciELO
language English
format Digital
author Santos,Izaias S.
Garcia,Carlos A. B.
Passos,Elisangela A.
Alves,Jose P. H.
spellingShingle Santos,Izaias S.
Garcia,Carlos A. B.
Passos,Elisangela A.
Alves,Jose P. H.
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
author_facet Santos,Izaias S.
Garcia,Carlos A. B.
Passos,Elisangela A.
Alves,Jose P. H.
author_sort Santos,Izaias S.
title Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_short Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_full Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_fullStr Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_full_unstemmed Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_sort distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast brazil
description The distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain.
publisher Sociedade Brasileira de Química
publishDate 2013
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011
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