Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol

Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol

Isoprenylation of aldehydes and ketones was directly performed by selective indium insertion on a mixture of 2-bromomethyl-1,3-butadiene and its vinylic isomers in good yields. A short synthesis of (±)-ipsenol, an aggregation pheromone of the Ips paraconfusus bark beetle, demonstrates the utility of this method in organic synthesis.

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Main Authors: Ceschi,Marco A., Petzhold,Cesar, Schenato,Rossana A.
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2003
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000500010
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spelling oai:scielo:S0103-505320030005000102004-02-10Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenolCeschi,Marco A.Petzhold,CesarSchenato,Rossana A. isoprenylation indium 2-bromomethyl-1,3-butadiene (±)-ipsenol Isoprenylation of aldehydes and ketones was directly performed by selective indium insertion on a mixture of 2-bromomethyl-1,3-butadiene and its vinylic isomers in good yields. A short synthesis of (±)-ipsenol, an aggregation pheromone of the Ips paraconfusus bark beetle, demonstrates the utility of this method in organic synthesis.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society v.14 n.5 20032003-10-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000500010en10.1590/S0103-50532003000500010
institution SCIELO
collection OJS
country Brasil
countrycode BR
component Revista
access En linea
databasecode rev-scielo-br
tag revista
region America del Sur
libraryname SciELO
language English
format Digital
author Ceschi,Marco A.
Petzhold,Cesar
Schenato,Rossana A.
spellingShingle Ceschi,Marco A.
Petzhold,Cesar
Schenato,Rossana A.
Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol
author_facet Ceschi,Marco A.
Petzhold,Cesar
Schenato,Rossana A.
author_sort Ceschi,Marco A.
title Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol
title_short Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol
title_full Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol
title_fullStr Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol
title_full_unstemmed Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol
title_sort indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol
description Isoprenylation of aldehydes and ketones was directly performed by selective indium insertion on a mixture of 2-bromomethyl-1,3-butadiene and its vinylic isomers in good yields. A short synthesis of (±)-ipsenol, an aggregation pheromone of the Ips paraconfusus bark beetle, demonstrates the utility of this method in organic synthesis.
publisher Sociedade Brasileira de Química
publishDate 2003
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000500010
work_keys_str_mv AT ceschimarcoa indiummediatedisoprenylationofcarbonylcompoundswith2bromomethyl13butadieneashortsynthesisofipsenol
AT petzholdcesar indiummediatedisoprenylationofcarbonylcompoundswith2bromomethyl13butadieneashortsynthesisofipsenol
AT schenatorossanaa indiummediatedisoprenylationofcarbonylcompoundswith2bromomethyl13butadieneashortsynthesisofipsenol
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