Prenylated Coumarins, Chalcone and New Cinnamic Acid and Dihydrocinnamic Acid Derivatives from Brosimum gaudichaudii

Three new natural cinnamic acid and dihydrocinnamic acid derivatives were isolated from the roots of Brosimum gaudichaudii, in addition to fourteen known substances (ten coumarins, one chalcone, beta-sitosterol, 3beta-O-beta-D-glucopyranosylsitosterol and beta-amyrin). The structures were established by spectral data, including analysis of 2D-NMR experiments and mass spectra. All aromatic compounds have 4-hydroxy-3-prenylcinnamic acid as a common precursor. The new substances are derived from a precursor of the coumarins, which through an O-methylation lost its ability to form the lactone ring.

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Main Authors: Monteiro,Verônica de F. F., Mathias,Leda, Vieira,Ivo J. C., Schripsema,Jan, Braz-Filho,Raimundo
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2002
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200023
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spelling oai:scielo:S0103-505320020002000232002-06-25Prenylated Coumarins, Chalcone and New Cinnamic Acid and Dihydrocinnamic Acid Derivatives from Brosimum gaudichaudiiMonteiro,Verônica de F. F.Mathias,LedaVieira,Ivo J. C.Schripsema,JanBraz-Filho,Raimundo Brosimum gaudichaudii Moraceae Coumarins Chalcone Cinnamic acid dihydrocinnamic acid derivatives Three new natural cinnamic acid and dihydrocinnamic acid derivatives were isolated from the roots of Brosimum gaudichaudii, in addition to fourteen known substances (ten coumarins, one chalcone, beta-sitosterol, 3beta-O-beta-D-glucopyranosylsitosterol and beta-amyrin). The structures were established by spectral data, including analysis of 2D-NMR experiments and mass spectra. All aromatic compounds have 4-hydroxy-3-prenylcinnamic acid as a common precursor. The new substances are derived from a precursor of the coumarins, which through an O-methylation lost its ability to form the lactone ring.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society v.13 n.2 20022002-01-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200023en10.1590/S0103-50532002000200023
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country Brasil
countrycode BR
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libraryname SciELO
language English
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author Monteiro,Verônica de F. F.
Mathias,Leda
Vieira,Ivo J. C.
Schripsema,Jan
Braz-Filho,Raimundo
spellingShingle Monteiro,Verônica de F. F.
Mathias,Leda
Vieira,Ivo J. C.
Schripsema,Jan
Braz-Filho,Raimundo
Prenylated Coumarins, Chalcone and New Cinnamic Acid and Dihydrocinnamic Acid Derivatives from Brosimum gaudichaudii
author_facet Monteiro,Verônica de F. F.
Mathias,Leda
Vieira,Ivo J. C.
Schripsema,Jan
Braz-Filho,Raimundo
author_sort Monteiro,Verônica de F. F.
title Prenylated Coumarins, Chalcone and New Cinnamic Acid and Dihydrocinnamic Acid Derivatives from Brosimum gaudichaudii
title_short Prenylated Coumarins, Chalcone and New Cinnamic Acid and Dihydrocinnamic Acid Derivatives from Brosimum gaudichaudii
title_full Prenylated Coumarins, Chalcone and New Cinnamic Acid and Dihydrocinnamic Acid Derivatives from Brosimum gaudichaudii
title_fullStr Prenylated Coumarins, Chalcone and New Cinnamic Acid and Dihydrocinnamic Acid Derivatives from Brosimum gaudichaudii
title_full_unstemmed Prenylated Coumarins, Chalcone and New Cinnamic Acid and Dihydrocinnamic Acid Derivatives from Brosimum gaudichaudii
title_sort prenylated coumarins, chalcone and new cinnamic acid and dihydrocinnamic acid derivatives from brosimum gaudichaudii
description Three new natural cinnamic acid and dihydrocinnamic acid derivatives were isolated from the roots of Brosimum gaudichaudii, in addition to fourteen known substances (ten coumarins, one chalcone, beta-sitosterol, 3beta-O-beta-D-glucopyranosylsitosterol and beta-amyrin). The structures were established by spectral data, including analysis of 2D-NMR experiments and mass spectra. All aromatic compounds have 4-hydroxy-3-prenylcinnamic acid as a common precursor. The new substances are derived from a precursor of the coumarins, which through an O-methylation lost its ability to form the lactone ring.
publisher Sociedade Brasileira de Química
publishDate 2002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200023
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