A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]

A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]

The synthesis, X-ray crystal structure, and spectroscopic properties of the new coordination compound [OV IV(HBIMETEN)], [H3BIMETEN = N , N' - (2-hydroxybenzil) -N-(1-methylimidazole-2-yl-methyl)-N'-hydroxyethil-ethylenediamine] are reported as V IV O2+ complex example containing phenolate and 1-methylimidazole coordinated simultaneously to the metal center. The EPR and UV-Vis properties of the title compound are similar to those observed in [OV IV(tf)].

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Bibliographic Details
Main Authors: Neves,Ademir, Romanowski,Stela Maris de Moraes, Vencato,Ivo, Mangrich,Antonio Salvio
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 1998
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500003
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