Sorption-Desorption Behavior of Imazethapyr and Imazapic on Six Brazilian Soils

ABSTRACT: The characterization of sorption-desorption for imazethapyr and imazapic in six agricultural soils was performed to assess the availability of these herbicides in pollution processes. In this pursuit, the batch equilibrium method and high-performance liquid chromatography were used. The magnitude of Kf values ranging from 0.38 to 2.52 mg1-n kg-1 Ln for imazethapyr and 0.43 to 2.72 mg1-n kg-1 Ln for imazapic indicate weak sorption in the evaluated soils. Soil pH (5.1 to 6.1) and iron oxalate affect sorption-desorption of both herbicides but the type and percentage of clay can be the main factor affecting these two processes. A high desorption percentage (>70%) was found in Regosol, Dystric Plinthosol, Ferralsol (for both herbicides), and Dystric Gleysol (only imazapic) soils, which implies in leaching risks of these imidazolinone herbicides into groundwater. Lower desorption (<50%) was found in Cambisol and Alisol (for both herbicides), and (~50%) in Dystric Gleysol (only imazethapyr) soils, indicating that these herbicides could potentially injure the sensitive crops grown in rotation.

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Bibliographic Details
Main Authors: MARINHO,M.I.C., SOUZA,W.M., CABRAL,M.F., CASTRO NETO,M.D., QUEIROZ,M.E.L.R., SILVA,A.A.
Format: Digital revista
Language:English
Published: Sociedade Brasileira da Ciência das Plantas Daninhas 2018
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-83582018000100342
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