ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES

ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES

In the last two decades, enantioselective organocatalysis has established itself as one of the three pillars of asymmetric catalysis. The rapid growth in the area is due to the rationalization of organocatalysis based on the generic modes of catalyst activation, being applied to several types of reactions, in a rather generic and predictable way and providing high enantioselectivities. This tutorial review presents the evolution of this area through a brief discussion on all generic modes of activation previously systematized in the literature: activation via enamine, iminium ion, hydrogen-bonding, counterion, SOMO, photoredox, carbene and phase-transfer, and the recent advances in the area.

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Main Authors: Finelli,Fernanda G., Santos,Bruno M. da S., Frota,Lívia C. R. M. da
Format: Digital revista
Language:Portuguese
Published: Sociedade Brasileira de Química 2019
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000400425
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spelling oai:scielo:S0100-404220190004004252019-05-21ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTESFinelli,Fernanda G.Santos,Bruno M. da S.Frota,Lívia C. R. M. da asymmetric catalysis organocatalysis mode of activation organocascade continuous-flow In the last two decades, enantioselective organocatalysis has established itself as one of the three pillars of asymmetric catalysis. The rapid growth in the area is due to the rationalization of organocatalysis based on the generic modes of catalyst activation, being applied to several types of reactions, in a rather generic and predictable way and providing high enantioselectivities. This tutorial review presents the evolution of this area through a brief discussion on all generic modes of activation previously systematized in the literature: activation via enamine, iminium ion, hydrogen-bonding, counterion, SOMO, photoredox, carbene and phase-transfer, and the recent advances in the area.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaQuímica Nova v.42 n.4 20192019-04-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000400425pt10.21577/0100-4042.20170334
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country Brasil
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libraryname SciELO
language Portuguese
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author Finelli,Fernanda G.
Santos,Bruno M. da S.
Frota,Lívia C. R. M. da
spellingShingle Finelli,Fernanda G.
Santos,Bruno M. da S.
Frota,Lívia C. R. M. da
ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES
author_facet Finelli,Fernanda G.
Santos,Bruno M. da S.
Frota,Lívia C. R. M. da
author_sort Finelli,Fernanda G.
title ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES
title_short ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES
title_full ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES
title_fullStr ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES
title_full_unstemmed ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES
title_sort organocatálise enantiosseletiva: evolução e aspectos recentes
description In the last two decades, enantioselective organocatalysis has established itself as one of the three pillars of asymmetric catalysis. The rapid growth in the area is due to the rationalization of organocatalysis based on the generic modes of catalyst activation, being applied to several types of reactions, in a rather generic and predictable way and providing high enantioselectivities. This tutorial review presents the evolution of this area through a brief discussion on all generic modes of activation previously systematized in the literature: activation via enamine, iminium ion, hydrogen-bonding, counterion, SOMO, photoredox, carbene and phase-transfer, and the recent advances in the area.
publisher Sociedade Brasileira de Química
publishDate 2019
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000400425
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AT frotaliviacrmda organocataliseenantiosseletivaevolucaoeaspectosrecentes
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