Sistema de injeção em fluxo espectrofotométrico para monitorar peróxido de hidrogênio em processo de fotodegradação por reação foto-Fenton

A flow injection spectrophotometric system was projected for monitoring hydrogen peroxide during photodegradation of organic contaminants in photo-Fenton processes (Fe2+/H2O2/UV). Sample is injected manually in a carrier stream and then receives by confluence a 0.1 mol L-1 NH4VO3 solution in 0.5 mol L-1 H2SO4 medium. The product formed shows absorption at 446 nm which is recorded as a peak with height proportional to H2O2 concentration. The performance of the proposed system was evaluated by monitoring the consumption of H2O2 during the photodegradation of dichloroacetic acid solution by foto-Fenton reaction.

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Bibliographic Details
Main Authors: Oliveira,Mirela C., Nogueira,Raquel F. Pupo, Gomes Neto,José A., Jardim,Wilson F., Rohwedder,Jarbas J. R.
Format: Digital revista
Language:Portuguese
Published: Sociedade Brasileira de Química 2001
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422001000200007
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