Methane dehydroaromatization catalyzed by Mo/ZSM-5 : location-steered activity and mechanism
This work examined the location-steered catalytic behavior of Mo/ZSM-5 catalyst for one-step methane dehydroaromatization to benzene reaction. The results indicated that α-site is the preferred location for the formation of ethylene, the main intermediate for aromatics production via the propagation pathway, while δ-site is favorable for the hydrocarbon pool aggregation reaction pathway.
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Format: | Article/Letter to editor biblioteca |
Language: | English |
Subjects: | Life Science, |
Online Access: | https://research.wur.nl/en/publications/methane-dehydroaromatization-catalyzed-by-mozsm-5-location-steere |
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Summary: | This work examined the location-steered catalytic behavior of Mo/ZSM-5 catalyst for one-step methane dehydroaromatization to benzene reaction. The results indicated that α-site is the preferred location for the formation of ethylene, the main intermediate for aromatics production via the propagation pathway, while δ-site is favorable for the hydrocarbon pool aggregation reaction pathway. |
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