Methane dehydroaromatization catalyzed by Mo/ZSM-5 : location-steered activity and mechanism

This work examined the location-steered catalytic behavior of Mo/ZSM-5 catalyst for one-step methane dehydroaromatization to benzene reaction. The results indicated that α-site is the preferred location for the formation of ethylene, the main intermediate for aromatics production via the propagation pathway, while δ-site is favorable for the hydrocarbon pool aggregation reaction pathway.

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Bibliographic Details
Main Author: Li, Guanna
Format: Article/Letter to editor biblioteca
Language:English
Subjects:Life Science,
Online Access:https://research.wur.nl/en/publications/methane-dehydroaromatization-catalyzed-by-mozsm-5-location-steere
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Summary:This work examined the location-steered catalytic behavior of Mo/ZSM-5 catalyst for one-step methane dehydroaromatization to benzene reaction. The results indicated that α-site is the preferred location for the formation of ethylene, the main intermediate for aromatics production via the propagation pathway, while δ-site is favorable for the hydrocarbon pool aggregation reaction pathway.