Water-side turbulence enhancement of ozone deposition to the ocean
A parameterization for the deposition velocity of an ocean-reactive atmospheric gas (such as ozone) is developed. The parameterization is based on integration of the turbulent-molecular transport equation (with a chemical source term) in the ocean. It extends previous work that only considered reactions within the oceanic molecular sublayer. The sensitivity of the ocean-side transport to reaction rate and wind forcing is examined. A more complicated case with a much more reactive thin surfactant layer is also considered. The full atmosphere-ocean deposition velocity is obtained by matching boundary conditions at the interface. For an assumed ocean reaction rate of 103 s¿1, the enhancement for ozone deposition by oceanic turbulence is found to be up to a factor of three for meteorological data obtained in a recent cruise off the East Coast of the U.S.
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Format: | Article/Letter to editor biblioteca |
Language: | English |
Subjects: | boundary-layer, dry deposition, fluxes, gas-exchange, parameterization, surface, trends, wind-speed, |
Online Access: | https://research.wur.nl/en/publications/water-side-turbulence-enhancement-of-ozone-deposition-to-the-ocea |
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dig-wur-nl-wurpubs-3813992024-12-04 Fairall, C.W. Helmig, D. Ganzeveld, L.N. Hare, J. Article/Letter to editor Atmospheric Chemistry and Physics 2007 (2007) 7 ISSN: 1680-7316 Water-side turbulence enhancement of ozone deposition to the ocean 2007 A parameterization for the deposition velocity of an ocean-reactive atmospheric gas (such as ozone) is developed. The parameterization is based on integration of the turbulent-molecular transport equation (with a chemical source term) in the ocean. It extends previous work that only considered reactions within the oceanic molecular sublayer. The sensitivity of the ocean-side transport to reaction rate and wind forcing is examined. A more complicated case with a much more reactive thin surfactant layer is also considered. The full atmosphere-ocean deposition velocity is obtained by matching boundary conditions at the interface. For an assumed ocean reaction rate of 103 s¿1, the enhancement for ozone deposition by oceanic turbulence is found to be up to a factor of three for meteorological data obtained in a recent cruise off the East Coast of the U.S. en application/pdf https://research.wur.nl/en/publications/water-side-turbulence-enhancement-of-ozone-deposition-to-the-ocea https://edepot.wur.nl/10281 boundary-layer dry deposition fluxes gas-exchange parameterization surface trends wind-speed Wageningen University & Research |
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boundary-layer dry deposition fluxes gas-exchange parameterization surface trends wind-speed boundary-layer dry deposition fluxes gas-exchange parameterization surface trends wind-speed |
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boundary-layer dry deposition fluxes gas-exchange parameterization surface trends wind-speed boundary-layer dry deposition fluxes gas-exchange parameterization surface trends wind-speed Fairall, C.W. Helmig, D. Ganzeveld, L.N. Hare, J. Water-side turbulence enhancement of ozone deposition to the ocean |
description |
A parameterization for the deposition velocity of an ocean-reactive atmospheric gas (such as ozone) is developed. The parameterization is based on integration of the turbulent-molecular transport equation (with a chemical source term) in the ocean. It extends previous work that only considered reactions within the oceanic molecular sublayer. The sensitivity of the ocean-side transport to reaction rate and wind forcing is examined. A more complicated case with a much more reactive thin surfactant layer is also considered. The full atmosphere-ocean deposition velocity is obtained by matching boundary conditions at the interface. For an assumed ocean reaction rate of 103 s¿1, the enhancement for ozone deposition by oceanic turbulence is found to be up to a factor of three for meteorological data obtained in a recent cruise off the East Coast of the U.S. |
format |
Article/Letter to editor |
topic_facet |
boundary-layer dry deposition fluxes gas-exchange parameterization surface trends wind-speed |
author |
Fairall, C.W. Helmig, D. Ganzeveld, L.N. Hare, J. |
author_facet |
Fairall, C.W. Helmig, D. Ganzeveld, L.N. Hare, J. |
author_sort |
Fairall, C.W. |
title |
Water-side turbulence enhancement of ozone deposition to the ocean |
title_short |
Water-side turbulence enhancement of ozone deposition to the ocean |
title_full |
Water-side turbulence enhancement of ozone deposition to the ocean |
title_fullStr |
Water-side turbulence enhancement of ozone deposition to the ocean |
title_full_unstemmed |
Water-side turbulence enhancement of ozone deposition to the ocean |
title_sort |
water-side turbulence enhancement of ozone deposition to the ocean |
url |
https://research.wur.nl/en/publications/water-side-turbulence-enhancement-of-ozone-deposition-to-the-ocea |
work_keys_str_mv |
AT fairallcw watersideturbulenceenhancementofozonedepositiontotheocean AT helmigd watersideturbulenceenhancementofozonedepositiontotheocean AT ganzeveldln watersideturbulenceenhancementofozonedepositiontotheocean AT harej watersideturbulenceenhancementofozonedepositiontotheocean |
_version_ |
1819150814590009344 |