Chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (Ananas erectifolius)
E-mail: delrio@irnase.csic.es (J.C. del Río)
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Format: | artículo biblioteca |
Language: | English |
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American Chemical Society
2007
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Subjects: | Curaua, Ananas erectifolius, lipids, lignin, pyrolysis, hydroxy monoesters, glyceryl esters, paper pulp, |
Online Access: | http://hdl.handle.net/10261/34682 |
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dig-irnas-es-10261-346822018-09-12T07:38:36Z Chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (Ananas erectifolius) Marques, Gisela Gutiérrez Suárez, Ana Río Andrade, José Carlos del Curaua Ananas erectifolius lipids lignin pyrolysis hydroxy monoesters glyceryl esters paper pulp E-mail: delrio@irnase.csic.es (J.C. del Río) The chemical composition of leaf fibers of curaua (Ananas erectifolius), an herbaceous plant native of Amazonia, was studied. Special attention was paid to the content and composition of lignin and lipophilic compounds. The analysis of lignin in the curaua fibers was performed “in situ” by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) and showed a lignin composition with a p-hydroxyphenyl:guaiacyl:syringyl units (H:G:S) molar proportion of 30:29:41 (S/G molar ratio of 1.4). The presence of p-hydroxycinnamic acids (p-coumaric and ferulic acids) in curaua fibers was revealed upon pyrolysis in the presence of tetramethylammonium hydroxide. On the other hand, the main lipophilic compounds, analysed by GC/MS, were series of long-chain n-fatty acids, n-fatty alcohols, α- and ω-hydroxyacids, monoglycerides, sterols and waxes. Other compounds, such as ω-hydroxy monoesters and ω-hydroxy acylesters of glycerol were also found in this fiber in high amounts. Peer reviewed 2011-04-15T08:32:24Z 2011-04-15T08:32:24Z 2007 artículo http://purl.org/coar/resource_type/c_6501 Journal of Agricultural and Food Chemistry 55: 1327-1336 (2007) http://hdl.handle.net/10261/34682 10.1021/jf062677x en open American Chemical Society |
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Curaua Ananas erectifolius lipids lignin pyrolysis hydroxy monoesters glyceryl esters paper pulp Curaua Ananas erectifolius lipids lignin pyrolysis hydroxy monoesters glyceryl esters paper pulp |
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Curaua Ananas erectifolius lipids lignin pyrolysis hydroxy monoesters glyceryl esters paper pulp Curaua Ananas erectifolius lipids lignin pyrolysis hydroxy monoesters glyceryl esters paper pulp Marques, Gisela Gutiérrez Suárez, Ana Río Andrade, José Carlos del Chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (Ananas erectifolius) |
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E-mail: delrio@irnase.csic.es (J.C. del Río) |
format |
artículo |
topic_facet |
Curaua Ananas erectifolius lipids lignin pyrolysis hydroxy monoesters glyceryl esters paper pulp |
author |
Marques, Gisela Gutiérrez Suárez, Ana Río Andrade, José Carlos del |
author_facet |
Marques, Gisela Gutiérrez Suárez, Ana Río Andrade, José Carlos del |
author_sort |
Marques, Gisela |
title |
Chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (Ananas erectifolius) |
title_short |
Chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (Ananas erectifolius) |
title_full |
Chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (Ananas erectifolius) |
title_fullStr |
Chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (Ananas erectifolius) |
title_full_unstemmed |
Chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (Ananas erectifolius) |
title_sort |
chemical characterization of lignin and lipophilic fractions from leaf fibers of curaua (ananas erectifolius) |
publisher |
American Chemical Society |
publishDate |
2007 |
url |
http://hdl.handle.net/10261/34682 |
work_keys_str_mv |
AT marquesgisela chemicalcharacterizationofligninandlipophilicfractionsfromleaffibersofcurauaananaserectifolius AT gutierrezsuarezana chemicalcharacterizationofligninandlipophilicfractionsfromleaffibersofcurauaananaserectifolius AT rioandradejosecarlosdel chemicalcharacterizationofligninandlipophilicfractionsfromleaffibersofcurauaananaserectifolius |
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1777664173117800448 |