Oxidation with air by ascorbate-driven quinone redox cycling
Transition metal-free oxidation with air at room temperature has been achieved by simply using ascorbate (vitamin C) and catalytic amounts of menadione (vitamin K3). A combination of the mentioned vitamins transforms atmospheric oxygen into hydrogen peroxide, which is able to oxidize arylboronic acids and other chemical moieties.
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Main Authors: | Silveira-Dorta, Gastón, Monzón, Diego M., Pinacho Crisóstomo, Fernando R., Martín, Tomás, Martín, Víctor S., Carrillo Fumero, Romen |
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Other Authors: | European Commission |
Format: | artículo biblioteca |
Published: |
Royal Society of Chemistry (UK)
2015
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Online Access: | http://hdl.handle.net/10261/181197 http://dx.doi.org/10.13039/501100000780 http://dx.doi.org/10.13039/501100003329 |
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