Oxidation with air by ascorbate-driven quinone redox cycling
Transition metal-free oxidation with air at room temperature has been achieved by simply using ascorbate (vitamin C) and catalytic amounts of menadione (vitamin K3). A combination of the mentioned vitamins transforms atmospheric oxygen into hydrogen peroxide, which is able to oxidize arylboronic acids and other chemical moieties.
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Royal Society of Chemistry (UK)
2015
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| Online Access: | http://hdl.handle.net/10261/181197 http://dx.doi.org/10.13039/501100000780 http://dx.doi.org/10.13039/501100003329 |
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dig-ipna-es-10261-1811972020-06-01T10:00:26Z Oxidation with air by ascorbate-driven quinone redox cycling Silveira-Dorta, Gastón Monzón, Diego M. Pinacho Crisóstomo, Fernando R. Martín, Tomás Martín, Víctor S. Carrillo Fumero, Romen European Commission Ministerio de Economía y Competitividad (España) Transition metal-free oxidation with air at room temperature has been achieved by simply using ascorbate (vitamin C) and catalytic amounts of menadione (vitamin K3). A combination of the mentioned vitamins transforms atmospheric oxygen into hydrogen peroxide, which is able to oxidize arylboronic acids and other chemical moieties. This research was supported by the European Commission (IMBRAIN project, FP7-REGPOT-2012-CT2012-31637-IMBRAIN), and the Spanish MECD CEI10/00018 and MINECO, co-financed by the European Regional Development Fund (ERDF), CTQ2011-28417-C02-01, and CTQ2011-22653. G.S.-D. thanks EU Social Fund (FSE) and ACIISI for a pre-doctoral fellowship. Peer Reviewed 2019-05-10T09:21:53Z 2019-05-10T09:21:53Z 2015 2019-05-10T09:21:53Z artículo http://purl.org/coar/resource_type/c_6501 Chem. Commun, 51(32): 7027-7030 (2015) 1359-7345 http://hdl.handle.net/10261/181197 10.1039/c5cc01519g 1364-548X http://dx.doi.org/10.13039/501100000780 http://dx.doi.org/10.13039/501100003329 #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/EC/FP7/316137 https://doi.org/10.1039/c5cc01519g Sí none Royal Society of Chemistry (UK) |
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Transition metal-free oxidation with air at room temperature has been achieved by simply using ascorbate (vitamin C) and catalytic amounts of menadione (vitamin K3). A combination of the mentioned vitamins transforms atmospheric oxygen into hydrogen peroxide, which is able to oxidize arylboronic acids and other chemical moieties. |
| author2 |
European Commission |
| author_facet |
European Commission Silveira-Dorta, Gastón Monzón, Diego M. Pinacho Crisóstomo, Fernando R. Martín, Tomás Martín, Víctor S. Carrillo Fumero, Romen |
| format |
artículo |
| author |
Silveira-Dorta, Gastón Monzón, Diego M. Pinacho Crisóstomo, Fernando R. Martín, Tomás Martín, Víctor S. Carrillo Fumero, Romen |
| spellingShingle |
Silveira-Dorta, Gastón Monzón, Diego M. Pinacho Crisóstomo, Fernando R. Martín, Tomás Martín, Víctor S. Carrillo Fumero, Romen Oxidation with air by ascorbate-driven quinone redox cycling |
| author_sort |
Silveira-Dorta, Gastón |
| title |
Oxidation with air by ascorbate-driven quinone redox cycling |
| title_short |
Oxidation with air by ascorbate-driven quinone redox cycling |
| title_full |
Oxidation with air by ascorbate-driven quinone redox cycling |
| title_fullStr |
Oxidation with air by ascorbate-driven quinone redox cycling |
| title_full_unstemmed |
Oxidation with air by ascorbate-driven quinone redox cycling |
| title_sort |
oxidation with air by ascorbate-driven quinone redox cycling |
| publisher |
Royal Society of Chemistry (UK) |
| publishDate |
2015 |
| url |
http://hdl.handle.net/10261/181197 http://dx.doi.org/10.13039/501100000780 http://dx.doi.org/10.13039/501100003329 |
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