Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio
Sixteen compounds incluiding four benzofurans (1–4), three benzoic acid derivatives (6–8), one eremophilane (9), four diterpenes (10–13) and four pyrrolizidine alkaloids (14–17) were isolated from Senecio subcandidus, S. klugii and S. ayapatensis from Perú. Compounds 1–4 and 6–9 have not been previously reported as natural products. Their molecular structures were determined by NMR spectroscopic analysis, comparison with published NMR data and chemical transformations. The X-ray analysis of acetylated derivative 5 and compound 7 were also performed. Their insecticidal and antifungal activities were tested.
Main Authors: | , , , , , , , |
---|---|
Other Authors: | |
Format: | artículo biblioteca |
Published: |
Elsevier
2018-12
|
Subjects: | Senecio, Benzofurans, Benzoic acid derivatives, Diterpenes, Pyrrolizidine alkaloids, Asteraceae, |
Online Access: | http://hdl.handle.net/10261/179474 http://dx.doi.org/10.13039/501100010198 http://dx.doi.org/10.13039/501100003339 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
dig-ipna-es-10261-179474 |
---|---|
record_format |
koha |
spelling |
dig-ipna-es-10261-1794742020-12-13T09:10:06Z Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio Ruiz-Vasquez, Liliana Ruiz-Mesía, Lastenia Reina, Matías López-Rodríguez, Matías González-Platas, Javier Giménez, Cristina Cabrera, Raimundo González-Coloma, Azucena Ministerio de Economía, Industria y Competitividad (España) Consejo Superior de Investigaciones Científicas (España) Senecio Benzofurans Benzoic acid derivatives Diterpenes Pyrrolizidine alkaloids Asteraceae Sixteen compounds incluiding four benzofurans (1–4), three benzoic acid derivatives (6–8), one eremophilane (9), four diterpenes (10–13) and four pyrrolizidine alkaloids (14–17) were isolated from Senecio subcandidus, S. klugii and S. ayapatensis from Perú. Compounds 1–4 and 6–9 have not been previously reported as natural products. Their molecular structures were determined by NMR spectroscopic analysis, comparison with published NMR data and chemical transformations. The X-ray analysis of acetylated derivative 5 and compound 7 were also performed. Their insecticidal and antifungal activities were tested. This work has been supported by Grant (CTQ2015-64049-C3-1-R) (MINECO/FEDER) Spain. LRV thanks JAEPRE-DOC-CSIC for predoctoral fellowship. Peer Reviewed 2019-04-05T16:05:01Z 2019-04-05T16:05:01Z 2018-12 2019-04-05T16:05:01Z artículo http://purl.org/coar/resource_type/c_6501 doi: 10.1016/j.phytol.2018.07.002 e-issn: 1876-7486 issn: 1874-3900 Phytochemistry Letters 28: 47-54 (2018) http://hdl.handle.net/10261/179474 10.1016/j.phytol.2018.07.002 http://dx.doi.org/10.13039/501100010198 http://dx.doi.org/10.13039/501100003339 #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-64049-C3-1-R Postprint https://doi.org/10.1016/j.phytol.2018.07.002 Sí none Elsevier |
institution |
IPNA ES |
collection |
DSpace |
country |
España |
countrycode |
ES |
component |
Bibliográfico |
access |
En linea |
databasecode |
dig-ipna-es |
tag |
biblioteca |
region |
Europa del Sur |
libraryname |
Biblioteca del IPNA España |
topic |
Senecio Benzofurans Benzoic acid derivatives Diterpenes Pyrrolizidine alkaloids Asteraceae Senecio Benzofurans Benzoic acid derivatives Diterpenes Pyrrolizidine alkaloids Asteraceae |
spellingShingle |
Senecio Benzofurans Benzoic acid derivatives Diterpenes Pyrrolizidine alkaloids Asteraceae Senecio Benzofurans Benzoic acid derivatives Diterpenes Pyrrolizidine alkaloids Asteraceae Ruiz-Vasquez, Liliana Ruiz-Mesía, Lastenia Reina, Matías López-Rodríguez, Matías González-Platas, Javier Giménez, Cristina Cabrera, Raimundo González-Coloma, Azucena Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio |
description |
Sixteen compounds incluiding four benzofurans (1–4), three benzoic acid derivatives (6–8), one eremophilane (9), four diterpenes (10–13) and four pyrrolizidine alkaloids (14–17) were isolated from Senecio subcandidus, S. klugii and S. ayapatensis from Perú. Compounds 1–4 and 6–9 have not been previously reported as natural products. Their molecular structures were determined by NMR spectroscopic analysis, comparison with published NMR data and chemical transformations. The X-ray analysis of acetylated derivative 5 and compound 7 were also performed. Their insecticidal and antifungal activities were tested. |
author2 |
Ministerio de Economía, Industria y Competitividad (España) |
author_facet |
Ministerio de Economía, Industria y Competitividad (España) Ruiz-Vasquez, Liliana Ruiz-Mesía, Lastenia Reina, Matías López-Rodríguez, Matías González-Platas, Javier Giménez, Cristina Cabrera, Raimundo González-Coloma, Azucena |
format |
artículo |
topic_facet |
Senecio Benzofurans Benzoic acid derivatives Diterpenes Pyrrolizidine alkaloids Asteraceae |
author |
Ruiz-Vasquez, Liliana Ruiz-Mesía, Lastenia Reina, Matías López-Rodríguez, Matías González-Platas, Javier Giménez, Cristina Cabrera, Raimundo González-Coloma, Azucena |
author_sort |
Ruiz-Vasquez, Liliana |
title |
Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio |
title_short |
Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio |
title_full |
Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio |
title_fullStr |
Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio |
title_full_unstemmed |
Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio |
title_sort |
benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from peruvian senecio |
publisher |
Elsevier |
publishDate |
2018-12 |
url |
http://hdl.handle.net/10261/179474 http://dx.doi.org/10.13039/501100010198 http://dx.doi.org/10.13039/501100003339 |
work_keys_str_mv |
AT ruizvasquezliliana benzofuransbenzoicacidderivativesditerpenesandpyrrolizidinealkaloidsfromperuviansenecio AT ruizmesialastenia benzofuransbenzoicacidderivativesditerpenesandpyrrolizidinealkaloidsfromperuviansenecio AT reinamatias benzofuransbenzoicacidderivativesditerpenesandpyrrolizidinealkaloidsfromperuviansenecio AT lopezrodriguezmatias benzofuransbenzoicacidderivativesditerpenesandpyrrolizidinealkaloidsfromperuviansenecio AT gonzalezplatasjavier benzofuransbenzoicacidderivativesditerpenesandpyrrolizidinealkaloidsfromperuviansenecio AT gimenezcristina benzofuransbenzoicacidderivativesditerpenesandpyrrolizidinealkaloidsfromperuviansenecio AT cabreraraimundo benzofuransbenzoicacidderivativesditerpenesandpyrrolizidinealkaloidsfromperuviansenecio AT gonzalezcolomaazucena benzofuransbenzoicacidderivativesditerpenesandpyrrolizidinealkaloidsfromperuviansenecio |
_version_ |
1777669749477474304 |