Synthesis of 1,4-epimine compounds. Iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation
4 pages, 1 table, 1 scheme.
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Elsevier
1985
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| Online Access: | http://hdl.handle.net/10261/17596 http://dx.doi.org/10.13039/501100007272 |
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dig-ipna-es-10261-175962009-10-26T23:00:00Z Synthesis of 1,4-epimine compounds. Iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation Armas, Pedro de Carrau, Reyes Concepción, José I. Francisco, Cosme G. Hernández, Rosendo Suárez, Ernesto Comisión Asesora de Investigación Científica y Técnica, CAICYT (España) Gobierno de Canarias 4 pages, 1 table, 1 scheme. Photolysis of several nitroamines, cianamines, and phosphoroamidates in the presence of iodosobenzene diacetate (IBDA) and iodine leads to neutral aminyl radicals which undergo intramolecular hydrogen abstraction to produce epimine compounds with yields that are favorably compared with those obtained with the system lead tetraacetate and iodine. This work was supported by the Investigation Programme of the Comisión Asesora de Investigación Científica y Técnica. P. de A. and J.I.C. express their gratitude to the Excmos. Cabildos Insulares de Tenerife and La Palma, respectively, for fellowships. 2009-10-09T09:38:39Z 2009-10-09T09:38:39Z 1985 artículo http://purl.org/coar/resource_type/c_6501 Tetrahedron Letters 26(20): 2493-2496 (1985) 0040-4039 http://hdl.handle.net/10261/17596 10.1016/S0040-4039(00)94862-7 http://dx.doi.org/10.13039/501100007272 en http://dx.doi.org/10.1016/S0040-4039(00)94862-7 none 2373 bytes 264815 bytes text/plain application/pdf Elsevier |
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English |
| description |
4 pages, 1 table, 1 scheme. |
| author2 |
Comisión Asesora de Investigación Científica y Técnica, CAICYT (España) |
| author_facet |
Comisión Asesora de Investigación Científica y Técnica, CAICYT (España) Armas, Pedro de Carrau, Reyes Concepción, José I. Francisco, Cosme G. Hernández, Rosendo Suárez, Ernesto |
| format |
artículo |
| author |
Armas, Pedro de Carrau, Reyes Concepción, José I. Francisco, Cosme G. Hernández, Rosendo Suárez, Ernesto |
| spellingShingle |
Armas, Pedro de Carrau, Reyes Concepción, José I. Francisco, Cosme G. Hernández, Rosendo Suárez, Ernesto Synthesis of 1,4-epimine compounds. Iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation |
| author_sort |
Armas, Pedro de |
| title |
Synthesis of 1,4-epimine compounds. Iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation |
| title_short |
Synthesis of 1,4-epimine compounds. Iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation |
| title_full |
Synthesis of 1,4-epimine compounds. Iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation |
| title_fullStr |
Synthesis of 1,4-epimine compounds. Iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation |
| title_full_unstemmed |
Synthesis of 1,4-epimine compounds. Iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation |
| title_sort |
synthesis of 1,4-epimine compounds. iodosobenzene diacetate, an efficient reagent for neutral nitrogen radical generation |
| publisher |
Elsevier |
| publishDate |
1985 |
| url |
http://hdl.handle.net/10261/17596 http://dx.doi.org/10.13039/501100007272 |
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